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Ionic Equilibrium question

2024 · 8 Apr · Shift 2 · Q2
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Ionic Equilibrium question

2024 · 8 Apr · Shift 2 · Q2

JEE MainChemistryIonic EquilibriumMCQ+4 / −1
Given below are two statements : Statement (I) : A Buffer solution is the mixture of a salt and an acid or a base mixed in any particular quantities Statement (II) : Blood is naturally occurring buffer solution whose pH\mathrm{pH}pH is maintained by H2CO3/HCO3⊖\mathrm{H}_2 \mathrm{CO}_3 / \mathrm{HCO}_3{ }^{\ominus}H2​CO3​/HCO3​⊖ concentrations. In the light of the above statements, choose the correct answer from the options given below :
  1. A
    Both Statement I and Statement II are false
  2. B
    Both Statement I and Statement II are true
  3. C
    Statement I is false but Statement II is true
  4. D
    Statement I is true but Statement II is false
View written solutionFree

Correct answer: C

  1. Analyze Statement (I)

    A buffer solution is not just any mixture of a salt and an acid or a base in any particular quantities.

    A buffer is specifically:

    • a weak acid + its conjugate base (salt), or
    • a weak base + its conjugate acid (salt)

    Also, the components must be present in suitable amounts so that the solution can resist change in pH.

    Examples:

    • Acidic buffer: CH3COOH+CH3COONa\mathrm{CH_3COOH + CH_3COONa}CH3​COOH+CH3​COONa
    • Basic buffer: NH4OH+NH4Cl\mathrm{NH_4OH + NH_4Cl}NH4​OH+NH4​Cl

    So Statement (I) is false because:

    • it does not specify weak acid/base,
    • and says any quantities, which is incorrect.
  2. Analyze Statement (II)

    Blood is a naturally occurring buffer solution.

    Its pH is maintained mainly by the bicarbonate buffer system: H2CO3/HCO3−\mathrm{H_2CO_3 / HCO_3^-}H2​CO3​/HCO3−​

    This is a standard biological buffer system helping maintain blood pH near 7.47.47.4.

    Therefore, Statement (II) is true.

  3. Choose the correct option

    • Statement (I): False
    • Statement (II): True

    Hence, the correct option is: C\boxed{\text{C}}C​

  4. Comparison with stored answer

    Stored correct answer: C

    My derived answer: C

    So, they agree.

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