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Ionic Equilibrium question

2002 · Shift 0 · Q5
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  5. /2002 · Shift 0 · Q5

Ionic Equilibrium question

2002 · Shift 0 · Q5

JEE MainChemistryIonic EquilibriumMCQ+4 / −1
1 M NaCL and 1 M HCL are present in an aqueous solution. The solution is
  1. A
    not a buffer solution with pH < 7
  2. B
    not a buffer solution with pH > 7
  3. C
    a buffer solution with pH < 7
  4. D
    a buffer solution with pH > 7
View written solutionFree

Correct answer: A

  1. Identify the components present

    The solution contains:

    • 1 M NaCl1\,\text{M } \mathrm{NaCl}1M NaCl
    • 1 M HCl1\,\text{M } \mathrm{HCl}1M HCl
  2. Check whether it can be a buffer

    A buffer solution requires:

    • a weak acid and its conjugate base, or
    • a weak base and its conjugate acid.

    Here:

    • HCl\mathrm{HCl}HCl is a strong acid
    • NaCl\mathrm{NaCl}NaCl is a salt of a strong acid (HCl\mathrm{HCl}HCl) and a strong base (NaOH\mathrm{NaOH}NaOH)

    Since neither a weak acid/base nor its conjugate pair is present, this solution cannot act as a buffer.

  3. Determine the pH nature of the solution

    HCl\mathrm{HCl}HCl is a strong acid and dissociates completely: HCl→H++Cl−\mathrm{HCl} \rightarrow \mathrm{H^+} + \mathrm{Cl^-}HCl→H++Cl−

    Since the concentration of HCl\mathrm{HCl}HCl is 1 M1\,\text{M}1M, [H+]≈1 M[\mathrm{H^+}] \approx 1\,\text{M}[H+]≈1M

    Therefore, pH=−log⁡(1)=0\mathrm{pH} = -\log(1) = 0pH=−log(1)=0

    So the solution has: pH<7\mathrm{pH} < 7pH<7

  4. Evaluate the options

    • A: not a buffer solution with pH<7\mathrm{pH}<7pH<7 ✅
    • B: not a buffer solution with pH>7\mathrm{pH}>7pH>7 ❌
    • C: a buffer solution with pH<7\mathrm{pH}<7pH<7 ❌
    • D: a buffer solution with pH>7\mathrm{pH}>7pH>7 ❌
  5. Final answer

    The solution is not a buffer and is acidic.

    Hence, the correct option is A.

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