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Chemical Bonding and Molecular Structure

115 questions · Chemistry · NEET
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Chemical Bonding and Molecular Structure

115 questions · Chemistry · NEET

  1. Match List-I with List-II Choose the correct answer from the options given below : Includes table2025 · Q104 · MCQ
  2. Identify the correct orders against the property mentioned A. H2​O>NH3​>CHCl3​-dipole moment B. XeF4​>XeO3​>XeF2​ - number of lone pairs on central atom C. O−H>C−H>N−O−…2025 · Q122 · MCQ
  3. Given below are two statements : Statement I: A hypothetical diatomic molecule with bond order zero is quite stable. Statement II: As bond order increases, the bond length increases. In the light of the above statements, choose the most…2025 · Q95 · MCQ
  4. Match List I with List II. Choose the correct answer from the options given below : Includes table2024 · Q101 · MCQ
  5. Given below are two statements: Statement I: The boiling point of hydrides of Group 16 elements follow the order H2​O>H2​Te>H2​Se>H2​S. …2024 · Q103 · MCQ
  6. Intramolecular hydrogen bonding is present in2024 · Q104 · MCQ
  7. Match List I with List II. Choose the correct answer from the options given below: Includes table2024 · Q116 · MCQ
  8. Identify the correct answer.2024 · Q145 · MCQ
  9. Which of the following molecules has "NON ZERO" dipole moment value?2024 · Q105 · MCQ
  10. Arrange the following compounds in increasing order of their solubilities in chloroform: NaCl,CH3​OH, cyclohexane, CH3​CN2024 · Q112 · MCQ
  11. Identify the incorrect statement about PCl5​.2024 · Q113 · MCQ
  12. Match List-I with List-II: Choose the correct answer from the options given below: Includes table2024 · Q139 · MCQ
  13. Which one of the following represents all isoelectronic species ?2023 · Q100 · MCQ
  14. Which one of the following statements is incorrect related to Molecular Orbital Theory?2023 · Q105 · MCQ
  15. Given below are two statements: Statement I : Hydrated chlorides and bromides of Ca,Sr and Ba on heating undergo hydrolysis. Statement II : Hydrated chlorides and bromides of Be and…2023 · Q113 · MCQ
  16. The correct order of dipole moments for molecules NH3​,H2​ S,CH4​ and HF, is:2023 · Q94 · MCQ
  17. Taking stability as the factor, which one of the following represents correct relationship?2023 · Q103 · MCQ
  18. Intermolecular forces are forces of attraction and repulsion between interacting particles that will include: A. dipole - dipole forces. B. dipole - induced dipole forces C. hydrogen bonding D. covalent bonding E. dispersion forces Choose…2023 · Q104 · MCQ
  19. Amongst the following, the total number of species NOT having eight electrons around central atom in its outer most shell, is NH3​,AlCl3​,BeCl2​,CCl4​,PCl5​ :2023 · Q91 · MCQ
  20. The correct order of energies of molecular orbitals of N2​ molecule, is2023 · Q92 · MCQ
  21. Match List-I with List-II : Choose the correct answer from the options given below : Includes table2022 · Q103 · MCQ
  22. The correct order of bond angles in the following compounds/species is :2022 · Q120 · MCQ
  23. Which amongst the following is incorrect statement?2022 · Q115 · MCQ
  24. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R) Assertion (A) : ICI is more reactive than I2 Reason (R) : I-CI bond is weaker than I-I bond. In the light of the above statements,…2022 · Q90 · MCQ
  25. Amongst the following which one will have maximum 'lone pair - lone pair' electron repulsions?2022 · Q97 · MCQ
  26. Match List - I with List - II : Choose the correct answer from the options given below. Includes table2021 · Q101 · MCQ
  27. The correct sequence of bond enthalpy of 'C-X' bond is :2021 · Q110 · MCQ
  28. Which of the following molecules is non-polar in nature?2021 · Q124 · MCQ
  29. BF3 is planar and electron deficient compound. Hybridization and number of electrons around the central atom, respectively are :2021 · Q95 · MCQ
  30. Identify a molecule which does not exist.2020 · Q113 · MCQ
  31. Which of the following set of molecules will have zero dipole moment?2020 · Q95 · MCQ
  32. The number of sigma (σ) and pi (π) bonds in pent-2-en-4-yne is -2019 · Q103 · MCQ
  33. The manganate and permanganate ions are tetrahedral due to :2019 · Q104 · MCQ
  34. The correct structure of tribromooctaoxide is :2019 · Q105 · MCQ
  35. Which of the following diatomic molecular species has only π bonds according to Molecular Orbital Theory?2019 · Q106 · MCQ
  36. Consider the following species : CN+ , CN– , NO and CN. Which one of these will have the highest bond order?2018 · Q103 · MCQ
  37. In the structure of ClF3 , the number of lone pairs of electrons on central atom ‘Cl’ is2018 · Q105 · MCQ
  38. The species, having bond angles of 120o is2017 · Q105 · MCQ
  39. Which of the following pairs of compounds is isostructural ?2017 · Q106 · Multiple correct
  40. Which one of the following pairs of species have the same bond order ?2017 · Q107 · MCQ
  41. Predict the correct order among the following :2016 · Q103 · MCQ
  42. Consider the molecules CH4, NH3 and H2O. Which of the given statements is false?2016 · Q104 · MCQ
  43. Which one of the following compounds shows the presence of intramolecular hydrogen bond?2016 · Q102 · MCQ
  44. Which of the following pairs of ions is isoelectronic and isostructural ?2016 · Q103 · Multiple correct
  45. The hybridizations of atomic orbitals of nitrogen in NO2+​, NO3−​ and NH4+​ respectively are2016 · Q104 · MCQ
  46. The correct geometry and hybridization for XeF4 are2016 · Q105 · MCQ
  47. Among the following, which one is a wrong statement ?2016 · Q106 · MCQ
  48. In which of the following pairs, both the species are not isostructural ?2015 · Q95 · MCQ
  49. Decreasing order of stability of O2, O2−, O2+ and O22− is2015 · Q96 · MCQ
  50. Which of the following species contains equal number of σ- and π-bonds ?2015 · Q92 · MCQ
  51. Which of the following options represents the correct bond order ?2015 · Q96 · MCQ
  52. Maximum bond angle at nitrogen is present in which of the following ?2015 · Q97 · MCQ
  53. The correct bond order in the following species is2015 · Q98 · MCQ
  54. Which of the following pairs of ions are isoelectronic and isostructural ?2015 · Q99 · MCQ
  55. Which of the following molecules has the maximum dipole moment ?2014 · Q106 · MCQ
  56. Which one of the following species has plane triangular shape ?2014 · Q107 · MCQ
  57. The pair of species that has the same bond order in the following is2013 · Q106 · MCQ
  58. In which of the following pair both the species have sp3 hybridization ?2013 · Q107 · MCQ
  59. The outer orbitals of C in ethane molecule can be considered to be hybridized to give three equivalent sp2 orbitals. The total number of sigma (σ) and pi (π) bonds in ethane molecule is2013 · Q108 · MCQ
  60. In which of the following ionization processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic.2013 · Q109 · MCQ
  61. Which of the following is electron-deficient ?2013 · Q105 · MCQ
  62. XeF2 is isostructural with2013 · Q106 · MCQ
  63. Dipole-induced dipole interactions are present in which of the following pairs2013 · Q107 · MCQ
  64. Which of the following is a polar molecule?2013 · Q108 · MCQ
  65. Which of the following is paramagnetic?2013 · Q109 · MCQ
  66. Identify the correct order of solubility in aqueous medium.2013 · Q98 · MCQ
  67. During change of O2 to O2−​ ion, the electron adds on which one of the following orbitals ?2012 · Q79 · MCQ
  68. Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them2012 · Q80 · MCQ
  69. Which one of the following pairs is isostructural (i.e., having the same shape and hybridization) ?2012 · Q113 · MCQ
  70. Which of the following species contains three bond pairs and one lone pair arround the central atom ?2012 · Q114 · MCQ
  71. Bond order of 1.5 is shown by2012 · Q115 · MCQ
  72. The pair of species with the same bond order is2012 · Q116 · MCQ
  73. The pairs of species of oxygen and their magnetic behaviours are noted below. Which of the following presents the correct description?2011 · Q56 · MCQ
  74. Which of the following structures is the most preferred and hence of lowest energy for SO3?2011 · Q78 · MCQ
  75. Which of the following has the minimum bond length ?2011 · Q109 · MCQ
  76. The correct order of increasing bond length of C − H, C − O, C − C and C=C is2011 · Q110 · MCQ
  77. Which of the two ions from the list given below that have the geometry that is explained by the same hybridization of orbitals, NO2−​. NO3−​, NH2−​, NH4+​, SCN−?2011 · Q111 · MCQ
  78. The pairs of species of oxygen and their magnetic behavior are noted below. Which of the following presents the correct description?2011 · Q112 · MCQ
  79. In which of the following molecules the central atom does not have sp3 hybridization?2010 · Q70 · MCQ
  80. Some of the properties of the two species, NO3−​ and H3​O+ are described below. Which one of them is current?2010 · Q71 · MCQ
  81. Which one of the following species does not exist under normal conditions?2010 · Q121 · MCQ
  82. In which of the following pairs of molecules/ ions, the central atoms have sp2 hybridisation ?2010 · Q122 · MCQ
  83. In which one of the following species the central atom has the type of hybridization which is not the same as that present in the other three ?2010 · Q123 · MCQ
  84. What is the dominant intermolecular force or bond that must be overcome in converting liquid CH3OH to a gas?2009 · Q113 · MCQ
  85. In which of the following molecules/ions BF3, NO2−​, NH2−​ and H2O, the central atom is sp2 hybridised?2009 · Q114 · MCQ
  86. According to MO theory which of the lists ranks the nitrogen species in terms of increasing bond order ?2009 · Q115 · MCQ
  87. Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them2008 · Q110 · MCQ
  88. The correct order of increasing bond angles in the following triatomic species is2008 · Q111 · MCQ
  89. In which of the following pairs, the two species are isostructural?2007 · Q97 · MCQ
  90. The correct order of C − O bond length among CO, CO32−​, CO2 is2007 · Q98 · MCQ
  91. The electronegativity difference berween N and F is greater than that between N and H yet the dipole moment of NH3 (1.5D) is larger than that of NF3 (0.2 D). This is because2006 · Q104 · MCQ
  92. Which of the following is not a correct statement?2006 · Q112 · MCQ
  93. Which of the following is not isostructural with SiCl4 ?2006 · Q113 · MCQ
  94. Which of the following species has a linear shape?2006 · Q114 · MCQ
  95. The correct order in which the O − O bond length increases in the following is2005 · Q108 · MCQ
  96. Which of the following molecules has trigonal planar geometry?2005 · Q109 · MCQ
  97. The surface tension of which of the following liquid is maximum ?2005 · Q110 · MCQ
  98. The correct sequence of increasing covalent character is represented by2005 · Q125 · MCQ
  99. Which of the following would have a permanent dipole moment?2005 · Q97 · MCQ
  100. In a regular octahedral molecule, MX6 the number of X − M − X bonds at 180o is2004 · Q102 · MCQ
  101. Among the following, the pair in which the two species are not isostructural is2004 · Q103 · MCQ
  102. H2O is dipolar, whereas BeF2 is not. It is because2004 · Q104 · MCQ
  103. In BrF3 molecule, the lone pairs occupy equatorial positions to minimize2004 · Q105 · MCQ
  104. Which one of the following statements is not correct for sigma- and pi- bonds formed between two carbon atoms?2003 · Q112 · MCQ
  105. Which of the following has pπ − dπ bonding?2002 · Q110 · MCQ
  106. In NO3− ion number of bond pair and lone pair of electrons on nitrogen atom are2002 · Q111 · MCQ
  107. Which of the following is isoelectronic?2002 · Q112 · MCQ
  108. Which of the following two are isostructural?2001 · Q111 · MCQ
  109. Nitrogen forms N2, but phosphorus does not form P2, however, it converts P4, reason is2001 · Q112 · MCQ
  110. In which of the following bond angle is maximum ?2001 · Q113 · MCQ
  111. In X - H --- Y, X and Y both are electronegative elements. Then2001 · Q114 · MCQ
  112. Which compound has planar structure?2000 · Q100 · MCQ
  113. dπ − pπ bond present in2000 · Q109 · MCQ
  114. Which species does not exhibit paramagnetism?2000 · Q110 · MCQ
  115. Right order of dissociation energy N2 and N2+ is2000 · Q111 · MCQ