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Chemical Bonding and Molecular Structure question

2013 · Q106
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Chemical Bonding and Molecular Structure question

2013 · Q106

NEETChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The pair of species that has the same bond order in the following is
  1. A
    CO, NO+
  2. B
    NO−-−, CN−-−
  3. C
    O2, N2
  4. D
    O2, B2
View written solutionFree

Correct answer: A

CO = + 8 = 14 electrons
NO+ = 7 + 8 - 1 = 14 electrons
Both have electronic configuration:
σ1s2\sigma 1s^2σ1s2 σ∗1s2\sigma^* 1s^2σ∗1s2 σ2s2\sigma 2s^2σ2s2 σ∗2s2\sigma^* 2s^2σ∗2s2 σ2pz2\sigma 2p_z^2σ2pz2​ σ2px2\sigma 2p_x^2σ2px2​ σ2py2\sigma 2p_y^2σ2py2​
Bond order = 10−4210 - 4 \over 2210−4​ = 3

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