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Chemical Bonding and Molecular Structure question

2024 · Q113
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Chemical Bonding and Molecular Structure question

2024 · Q113

NEETChemistryChemical Bonding and Molecular StructureMCQ+4 / −1

Identify the incorrect statement about PCl5\mathrm{PCl}_5PCl5​.

  1. A
    PCl5\mathrm{PCl}_5PCl5​ possesses two different Cl−P−Cl\mathrm{Cl}-\mathrm{P}-\mathrm{Cl}Cl−P−Cl bond angles
  2. B
    All five P−Cl\mathrm{P}-\mathrm{Cl}P−Cl bonds are identical in length
  3. C
    PCl5\mathrm{PCl}_5PCl5​ exhibits sp3ds p^3 dsp3d hybridisation
  4. D
    PCl5\mathrm{PCl}_5PCl5​ consists of five P−Cl\mathrm{P}-\mathrm{Cl}P−Cl (sigma) bonds
View written solutionFree

Correct answer: B

NEET 2024 (Re-Examination) Chemistry - Chemical Bonding and Molecular Structure Question 4 English Explanation

It is $s p^3 d$ hybridised with axial to equatorial angle of $90^{\circ}$ and equatorial bond angles of $120^{\circ}$. It has five $$\mathrm{P}-\mathrm{Cl}$$ sigma bonds.

Axial bonds are longer than equatorial bonds.

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