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Chemical Bonding and Molecular Structure question

2008 · Q110
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Chemical Bonding and Molecular Structure question

2008 · Q110

NEETChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them
  1. A
    NO<O2−<C22−<He2+NO \lt {O_2}^ - \lt {C_2}^{2 - } \lt He_2^ +NO<O2​−<C2​2−<He2+​
  2. B
    O2−<NO<C22−<He2+{O_2}^ - \lt NO \lt {C_2}^{2 - } \lt He_2^ +O2​−<NO<C2​2−<He2+​
  3. C
    C22−<He2+<O2−<NO{C_2}^{2 - } \lt He_2^ + \lt {O_2}^ - \lt NOC2​2−<He2+​<O2​−<NO
  4. D
    He2+<O2−<NO<C22−He_2^ + \lt {O_2}^ - \lt NO \lt {C_2}^{2 - }He2+​<O2​−<NO<C2​2−
View written solutionFree

Correct answer: D

Molecular orbital configuration of NO (15 electrons) is

σ1s2 σ1s2∗ σ2s2 σ2s2∗ σ2pz2 π2px2 = π2py2 π2px1∗ = π2pyo∗{\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\sigma _{2p_z^2}}\,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}\,\pi _{2p_x^1}^ * \, = \,\pi _{2p_y^o}^ * σ1s2​σ1s2∗​σ2s2​σ2s2∗​σ2pz2​​π2px2​​=π2py2​​π2px1​∗​=π2pyo​∗​

∴    \therefore\,\,\,\,∴ Nb = 10

Na = 5

∴    \therefore\,\,\,\,∴ BO = 12[10−5]{1 \over 2}\left[ {10 - 5} \right]21​[10−5] = 2.5

Molecular orbital configuration of O2−O_2^ - O2−​ (17 electrons) is

σ1s2 σ1s2∗ σ2s2 σ2s2∗ σ2pz2 π2px2 = π2py2 π2px2∗ = π2py1∗{\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\sigma _{2p_z^2}}\,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}\,\pi _{2p_x^2}^ * \, = \,\pi _{2p_y^1}^ * σ1s2​σ1s2∗​σ2s2​σ2s2∗​σ2pz2​​π2px2​​=π2py2​​π2px2​∗​=π2py1​∗​

∴    \therefore\,\,\,\,∴ Nb = 10

Na = 7

∴    \therefore\,\,\,\,∴ BO = 12[10−7]{1 \over 2}\left[ {10 - 7} \right]21​[10−7] = 1.5

Molecular orbital configuration of C22−C_2^ {2-} C22−​ (14 electrons) is

σ1s2 σ1s2∗ σ2s2 σ2s2∗ π2px2 = π2py2 σ2pz2{\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}\,{\sigma _{2p_z^2}}σ1s2​σ1s2∗​σ2s2​σ2s2∗​π2px2​​=π2py2​​σ2pz2​​

∴    \therefore\,\,\,\,∴ Nb = 10

Na = 4

∴    \therefore\,\,\,\,∴ BO = 12[10−4]{1 \over 2}\left[ {10 - 4} \right]21​[10−4] = 3

   \,\,\, Configuration of He2+He_2^ + He2+​ (3 electrons) is = σ1s2{\sigma _{1{s^2}}}σ1s2​ σ1s1∗\sigma _{1{s^1}}^ * σ1s1∗​

∴   \therefore\,\,\,∴ Bond order = 12{1 \over 2}21​ (2 −-−1) = 0.5

∴\therefore∴ Correct order is :

He2+<O2−<NO<C22−He_2^ + \lt {O_2}^ - \lt NO \lt {C_2}^{2 - }He2+​<O2​−<NO<C2​2−

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