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Chemistry · 2005 · Shift 0

59 questions from this JEE Main paper
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Chemistry · 2005 · Shift 0

59 questions from this JEE Main paper

Chemical Equilibrium3 questionsThermodynamics3 questionsSolutions3 questionsIonic Equilibrium3 questionsChemical Bonding and Molecular Structure2 questionsBasics of Organic Chemistry3 questionsHydrocarbons4 questionsAlcohols Phenols and Ethers2 questionsCompounds Containing Nitrogen3 questionsBiomolecules1 questionsAldehydes Ketones and Carboxylic Acids3 questionsChemical Kinetics and Nuclear Chemistry5 questionsD and F Block Elements5 questionsStructure of Atom3 questionsElectrochemistry4 questionsCoordination Compounds5 questionsHaloalkanes and Haloarenes3 questionsSome Basic Concepts of Chemistry2 questionsPeriodic Table and Periodicity2 questions
  1. Q1.An amount of solid NH4​HS is placed in a flask already containing ammonia gas at a certain temperature and 0.50 atm. Pressure. Ammonium hydrogen sulphide decomposes to yield NH3​ and H2​S gases in the flask. When the decomposition…
    Chemistry · Chemical Equilibrium · MCQ
  2. Q2.Consider the reaction: N2​ + 3H2​ → 2NH3​ carried out at constant temperature and pressure. If ΔH and ΔU are the enthalpy and internal energy changes for the reaction, which of the following expressions is true?
    Chemistry · Thermodynamics · MCQ
  3. Q3.If the bond dissociation energies of XY, X2​ and Y2​ (all diatomic molecules) are in the ratio of 1:1:0.5 and ΔHf​ for the formation of XY is -200 kJ mole-1. The bond dissociation energy of X2​ will be :
    Chemistry · Thermodynamics · MCQ
  4. Q4.Consider an endothermic reaction, X → Y with the activation energies Eb and Ef for the backward and forward reactions, respectively. In general :
    Chemistry · Thermodynamics · MCQ
  5. Q5.If α is the degree of dissociation of Na2​SO4​, the vant Hoff’s factor (i) used for calculating the molecular mass is :
    Chemistry · Solutions · MCQ
  6. Q6.The solubility product of a salt having general formula MX2​, in water is: 4 × 10-12 . The concentration of M2+ ions in the aqueous solution of the salt is :
    Chemistry · Ionic Equilibrium · MCQ
  7. Q7.The exothermic formation of ClF3​ is represented by the equation: Cl2​ (g) + 3F2​ (g) ⇋ 2ClF3​ (g); ΔH = -329 kJ Which of the following will increase the quantity of ClF3​ in an equilibrium mixture of…
    Chemistry · Chemical Equilibrium · MCQ
  8. Q8.For the reaction 2NO2​ (g) ⇋ 2NO (g) + O2​ (g), (Kc = 1.8 × 10-6 at 184oC) (R = 0.0831 kJ/(mol. K)) When Kp and Kc are compared at 184oC , it is found that :
    Chemistry · Chemical Equilibrium · MCQ
  9. Q9.What is the conjugate base of OH−?
    Chemistry · Ionic Equilibrium · MCQ
  10. Q10.Hydrogen ion concentration in mol / L in a solution of pH = 5.4 will be :
    Chemistry · Ionic Equilibrium · MCQ
  11. Q11.Which one of the following species is diamagnetic in nature?
    Chemistry · Chemical Bonding and Molecular Structure · MCQ
  12. Q12.Due to the presence of an unpaired electron, free radicals are:
    Chemistry · Basics of Organic Chemistry · MCQ
  13. Q13.Reaction of one molecule of HBr with one molecule of 1,3-butadiene at 40oC gives predominantly
    Chemistry · Hydrocarbons · MCQ
  14. Q14.Of the five isomeric hexanes, the isomer which can give two monochlorinated compounds is
    Chemistry · Hydrocarbons · MCQ
  15. Q15.2 methylbutane on reacting with bromine in the presence of sunlight gives mainly
    Chemistry · Hydrocarbons · MCQ
  16. Q16.Acid catalyzed hydration of alkenes except ethene leads to the formation of
    Chemistry · Alcohols Phenols and Ethers · MCQ
  17. Q17.Which types of isomerism is shown by 2,3-dichlorobutane?
    Chemistry · Hydrocarbons · MCQ
  18. Q18.Benzene and toluene form nearly ideal solutions. At 20 oC, the vapour pressure of benzene is 75 torr and that of toluene is 22 torr. The partial vapour pressure of benzene at 20 oC for a solution containing 78 g of benzene and 46 g of…
    Chemistry · Solutions · MCQ
  19. Q19.Equimolar solutions in the same solvent have
    Chemistry · Solutions · MCQ
  20. Q20.Amongst the following the most basic compound is
    Chemistry · Compounds Containing Nitrogen · MCQ
  21. Q21.Which one of the following methods is neither meant for the synthesis nor for separation of amines?
    Chemistry · Compounds Containing Nitrogen · MCQ
  22. Q22.An organic compound having molecular mass 60 is found to contain C = 20%, H = 6.67% and N = 46.67% while rest is oxygen. On heating it gives NH3​ along with a solid residue. The solid residue give violet colour with alkaline copper…
    Chemistry · Compounds Containing Nitrogen · MCQ
  23. Q23.In both DNA and RNA, heterocyclic base and phosphate ester linkages are at-
    Chemistry · Biomolecules · MCQ
  24. Q24.Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of an acid forms a compound if water during the reaction is continuously removed. The compound formed is generally known as
    Chemistry · Aldehydes Ketones and Carboxylic Acids · MCQ
  25. Q25.The decreasing order of nucleophilicity among the nucleophiles Includes diagram
    Chemistry · Basics of Organic Chemistry · MCQ
  26. Q26.The reaction is fastest when X is Includes diagram
    Chemistry · Basics of Organic Chemistry · MCQ
  27. Q27.A schematic plot of lnKeq​ versus inverse of temperature for a reaction is shown below The reaction must be Includes diagram
    Chemistry · Chemical Kinetics and Nuclear Chemistry · MCQ
  28. Q28.p-cresol reacts with chloroform in alkaline medium to give the compound A which adds hydrogen cyanide to form, the compound B. The latter on acidic hydrolysis gives chiral carboxylic acid. The structure of the carboxylic acid is :
    Chemistry · Aldehydes Ketones and Carboxylic Acids · MCQ
  29. Q29.The oxidation state of chromium in the final product formed the reaction between KI and acidified potassium dichromate solution is :
    Chemistry · D and F Block Elements · MCQ
  30. Q30.On heating mixture of Cu2​O and Cu2​S will give :
    Chemistry · D and F Block Elements · MCQ
  31. Q31.Calomel (Hg2​Cl2​) on reaction with ammonium hydroxide gives :
    Chemistry · D and F Block Elements · MCQ
  32. Q32.Pick out the isoelectronic structure from the following : ​(i)CH3​+(ii)H3​O+(iii)NH3​(iv)CH3​−​…
    Chemistry · Structure of Atom · MCQ
  33. Q33.For a spontaneous reaction the ∆G , equilibrium constant (K) and Ecello​ will be respectively
    Chemistry · Electrochemistry · MCQ
  34. Q34.Aluminium oxide may be electrolysed at 1000oC to furnish aluminium metal (Atomic mass = 27 amu; 1 Faraday = 96,500 Coulombs). The cathode reaction is Al3+ + 3e− → Alo To prepare 5.12 kg of aluminium metal by this method would…
    Chemistry · Electrochemistry · MCQ
  35. Q35.The highest electrical conductivity of the following aqueous solutions is of :
    Chemistry · Electrochemistry · MCQ
  36. Q36.Calculate ∧HOAc∞​ Using appropriate molar conductances of the electrolytes listed above at infinite dilution in H2O at 25oC Includes table
    Chemistry · Electrochemistry · MCQ
  37. Q37.Hydrogen bomb is based on the principle of
    Chemistry · Chemical Kinetics and Nuclear Chemistry · MCQ
  38. Q38.A reaction involving two different reactants can never be
    Chemistry · Chemical Kinetics and Nuclear Chemistry · MCQ
  39. Q39.The photon of hard gamma radiation knocks a proton out of 1224​Mg nucleus to form
    Chemistry · Chemical Kinetics and Nuclear Chemistry · MCQ
  40. Q40.t1/4 can be taken as the time taken for the concentration of a reactant to drop to 43​ of its initial value. If the rate constant for a first order reaction is K, the t1/4 can be written as
    Chemistry · Chemical Kinetics and Nuclear Chemistry · MCQ
  41. Q41.The lanthanide contraction is responsible for the fact that :
    Chemistry · D and F Block Elements · MCQ
  42. Q42.Which of the following factors may be regarded as the main cause of lanthanide contraction?
    Chemistry · D and F Block Elements · MCQ
  43. Q43.The IUPAC name of the coordination compound K3​[Fe(CN)6​] is
    Chemistry · Coordination Compounds · MCQ
  44. Q44.The oxidation state of Cr in [Cr(NH3​)4​Cl2​]+ is :
    Chemistry · Coordination Compounds · MCQ
  45. Q45.Which of the following compounds shows optical isomerism?
    Chemistry · Coordination Compounds · MCQ
  46. Q46.The value of the ‘spin only’ magnetic moment for one of the following configurations is 2.84 BM. The correct one is :
    Chemistry · Coordination Compounds · MCQ
  47. Q47.Which one of the following cyano complexes would exhibit the lowest value of paramagnetic behaviour? (At. No. Cr = 24, Mn = 25, Fe = 26, Co = 27)
    Chemistry · Coordination Compounds · MCQ
  48. Q48.Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of
    Chemistry · Haloalkanes and Haloarenes · MCQ
  49. Q49.Elimination of bromine from 2-bromobutane results in the formation of-
    Chemistry · Haloalkanes and Haloarenes · MCQ
  50. Q50.Alkyl halides react with dialkyl copper reagents to give
    Chemistry · Haloalkanes and Haloarenes · MCQ
  51. Q51.The best reagent to convert pent -3- en-2-ol into pent -3-en-2-one is
    Chemistry · Alcohols Phenols and Ethers · MCQ
  52. Q52.Among the following acids which has the lowest pKa value?
    Chemistry · Aldehydes Ketones and Carboxylic Acids · MCQ
  53. Q53.Two solutions of a substance (non electrolyte) are mixed in the following manner. 480 ml of 1.5 M first solution + 520 ml of 1.2 M second solution. What is the molarity of the final mixture?
    Chemistry · Some Basic Concepts of Chemistry · MCQ
  54. Q54.If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass unit, the mass of one mole of the substance will
    Chemistry · Some Basic Concepts of Chemistry · MCQ
  55. Q55.Of the following sets which one does NOT contain isoelectronic species?
    Chemistry · Structure of Atom · MCQ
  56. Q56.In a multi-electron atom, which of the following orbitals described by the three quantum members will have the same energy in the absence of magnetic and electric fields? (A) n = 1, l = 0, m = 0 (B) n = 2, l = 0, m = 0 (C) n = 2, l = 1, m…
    Chemistry · Structure of Atom · MCQ
  57. Q57.Which of the following oxides is amphoteric in character?
    Chemistry · Periodic Table and Periodicity · MCQ
  58. Q58.In which of the following arrangements the order is NOT according to the property indicated against it?
    Chemistry · Periodic Table and Periodicity · MCQ
  59. Q59.Lattice energy of an ionic compounds depends upon
    Chemistry · Chemical Bonding and Molecular Structure · MCQ