JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Among the following acids which has the lowest pKa value?
- A
- BHCOOH
- C
- D
View written solutionFree
Correct answer: B
-
We need to identify the acid with the lowest .
Lower means stronger acid. -
Given acids:
- A: = acetic acid
- B: = formic acid
- C: (intended as a more alkyl-substituted carboxylic acid)
- D: = propionic acid
-
Key principle:
In carboxylic acids, electron-donating alkyl groups increase electron density on the carboxylate ion and destabilize the conjugate base, making the acid weaker. Hence, more alkyl substitution means higher . -
Compare the acids:
- has no alkyl group attached.
- has one methyl group.
- has an ethyl group, which is electron-donating.
- is even more alkyl-substituted/electron-donating.
Therefore, acidity order is approximately:
So the corresponding order is:
-
Hence, the lowest is for .
-
Option check:
- A: — not lowest
- B: — lowest
- C: — not lowest
- D: — not lowest
Final answer: B
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