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Coordination Compounds question

2005 · Shift 0 · Q44
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Coordination Compounds question

2005 · Shift 0 · Q44

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
The oxidation state of Cr in [Cr(NH3)4Cl2]+[Cr(NH_3)_4Cl_2]^+[Cr(NH3​)4​Cl2​]+ is :
  1. A
    +3
  2. B
    +2
  3. C
    +1
  4. D
    0
View written solutionFree

Correct answer: A

  1. Let the oxidation state of chromium in [Cr(NH3)4Cl2]+[Cr(NH_3)_4Cl_2]^+[Cr(NH3​)4​Cl2​]+ be xxx.

  2. Determine the charge contributed by each ligand:

    • NH3NH_3NH3​ is a neutral ligand, so each NH3NH_3NH3​ contributes 000.
    • Cl−Cl^-Cl− is an anionic ligand, so each ClClCl contributes −1-1−1.
  3. The overall charge on the complex is +1+1+1. Therefore, x+4(0)+2(−1)=+1x + 4(0) + 2(-1) = +1x+4(0)+2(−1)=+1

  4. Simplify: x−2=1x - 2 = 1x−2=1 x=3x = 3x=3

  5. Hence, the oxidation state of Cr is: +3\boxed{+3}+3​

  6. Checking options:

    • A: +3+3+3 ✅
    • B: +2+2+2 ❌
    • C: +1+1+1 ❌
    • D: 000 ❌

Therefore, the correct option is A.

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