- ADiastereo
- BOptical
- CGeometric
- DStructural
View written solutionFree
Correct answer: A, B
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Write the structure of -dichlorobutane
The compound is:
Carbon-2 and carbon-3 are both attached to four different groups, so both are chiral centers.
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Check for optical isomerism
Since the molecule has two stereogenic centers, it can form stereoisomers:
- or
The pair and are non-superimposable mirror images, so the compound shows optical isomerism.
-
Check for diastereomerism
The meso form is not a mirror image of or . Therefore, these are diastereomers of each other.
So, -dichlorobutane also shows diastereoisomerism.
-
Check for geometric isomerism
Geometrical isomerism requires restricted rotation, usually due to a double bond or ring system. Here, there is no such restriction.
Hence, geometrical isomerism is not shown.
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Check for structural isomerism
Structural isomerism means same molecular formula but different connectivity. The question asks about -dichlorobutane itself; its characteristic isomerism here is stereoisomerism, not structural isomerism.
-
Evaluate options
- A: Diastereo → Yes
- B: Optical → Yes
- C: Geometric → No
- D: Structural → No
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Conclusion
-dichlorobutane shows both optical and diastereoisomerism. Since this is given as a single-correct MCQ, the stored answer is incomplete/incorrect because option is also correct.
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