JEE MainChemistryElectrochemistryMCQ+4 / −1
For a spontaneous reaction the ∆G , equilibrium constant (K) and will be respectively
- A-ve, >1, +ve
- B+ve, >1, -ve
- C-ve, <1, -ve
- D-ve, >1, -ve
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Correct answer: A
-
For a spontaneous reaction, the Gibbs free energy change must be negative:
-
The relation between standard free energy change and equilibrium constant is: For spontaneity under standard conditions, , so: Since , this implies:
-
The relation between free energy and cell potential is: For a spontaneous cell reaction, , hence: Since , we get:
-
Therefore, for a spontaneous reaction:
- is negative
- is positive
-
Checking options:
- A: ✅
- B: ❌
- C: ❌
- D: ❌
Hence, the correct option is A.
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