JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The oxidation state of chromium in the final product formed the reaction between and acidified potassium dichromate solution is :
- A
- B
- C
- D
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Correct answer: A
-
Identify the reacting species
Acidified potassium dichromate contains the dichromate ion, , in which chromium is in the oxidation state .
Potassium iodide provides iodide ions, , which act as a reducing agent.
-
Determine what happens in acidic medium
In acidic medium, dichromate is a strong oxidizing agent and gets reduced.
The reduction half-reaction is:
So chromium goes from oxidation state to .
-
Oxidation of iodide
Iodide gets oxidized to iodine:
Multiplying by to balance electrons:
-
Overall balanced reaction
Adding the two half-reactions:
-
Final oxidation state of chromium
In the final product, chromium is present as .
Therefore, the oxidation state of chromium is:
-
Option check
- A: ✅ Correct
- B: ❌ Incorrect
- C: ❌ Incorrect
- D: ❌ Incorrect
Hence, the correct answer is A.
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