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D and F Block Elements question

2005 · Shift 0 · Q29
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D and F Block Elements question

2005 · Shift 0 · Q29

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The oxidation state of chromium in the final product formed the reaction between KIK{\rm I}KI and acidified potassium dichromate solution is :
  1. A
    +3+3+3
  2. B
    +2+2+2
  3. C
    +6+6+6
  4. D
    +4+4+4
View written solutionFree

Correct answer: A

  1. Identify the reacting species

    Acidified potassium dichromate contains the dichromate ion, Cr2O72−\mathrm{Cr_2O_7^{2-}}Cr2​O72−​, in which chromium is in the oxidation state +6+6+6.

    Potassium iodide provides iodide ions, I−\mathrm{I^-}I−, which act as a reducing agent.

  2. Determine what happens in acidic medium

    In acidic medium, dichromate is a strong oxidizing agent and gets reduced.

    The reduction half-reaction is: Cr2O72−+14H++6e−→2Cr3++7H2O\mathrm{Cr_2O_7^{2-} + 14H^+ + 6e^- \rightarrow 2Cr^{3+} + 7H_2O}Cr2​O72−​+14H++6e−→2Cr3++7H2​O

    So chromium goes from oxidation state +6+6+6 to +3+3+3.

  3. Oxidation of iodide

    Iodide gets oxidized to iodine: 2I−→I2+2e−\mathrm{2I^- \rightarrow I_2 + 2e^-}2I−→I2​+2e−

    Multiplying by 333 to balance electrons: 6I−→3I2+6e−\mathrm{6I^- \rightarrow 3I_2 + 6e^-}6I−→3I2​+6e−

  4. Overall balanced reaction

    Adding the two half-reactions: Cr2O72−+14H++6I−→2Cr3++3I2+7H2O\mathrm{Cr_2O_7^{2-} + 14H^+ + 6I^- \rightarrow 2Cr^{3+} + 3I_2 + 7H_2O}Cr2​O72−​+14H++6I−→2Cr3++3I2​+7H2​O

  5. Final oxidation state of chromium

    In the final product, chromium is present as Cr3+\mathrm{Cr^{3+}}Cr3+.

    Therefore, the oxidation state of chromium is: +3\boxed{+3}+3​

  6. Option check

    • A: +3+3+3 ✅ Correct
    • B: +2+2+2 ❌ Incorrect
    • C: +6+6+6 ❌ Incorrect
    • D: +4+4+4 ❌ Incorrect

Hence, the correct answer is A.

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