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Correct answer: 5
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We need to identify the product
Aformed when thiosulphate ion, , is oxidized by permanganate, , in mildly alkaline medium. -
Thiosulphate commonly undergoes oxidation to tetrathionate under mild oxidizing conditions: So here,
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Now find the oxidation states of sulphur in .
The structure of tetrathionate can be viewed as: There are two kinds of sulphur atoms:
- the two terminal sulphur atoms bonded to oxygen are each at oxidation state
- the two inner sulphur atoms are each at oxidation state
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Check by average oxidation state method: Let average oxidation state of sulphur be . Then, This is only the average, not the oxidation state of each sulphur atom.
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Since the question asks for the oxidation state of sulphur in product , and in tetrathionate sulphur exists in two oxidation states, the oxidized sulphur atoms are at .
Thus, the required oxidation state is:
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