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D and F Block Elements question

2021 · 26 Feb · Shift 2 · Q19
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D and F Block Elements question

2021 · 26 Feb · Shift 2 · Q19

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
In mildly alkaline medium, thiosulphate ion is oxidized by MnO4−MnO_4^ -MnO4−​ to "A". The oxidation state of sulphur in "A" is ‾\underline{\hspace{2cm}}​.
Numerical answer
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Correct answer: 5

  1. We need to identify the product A formed when thiosulphate ion, S2O32−\mathrm{S_2O_3^{2-}}S2​O32−​, is oxidized by permanganate, MnO4−\mathrm{MnO_4^-}MnO4−​, in mildly alkaline medium.

  2. Thiosulphate commonly undergoes oxidation to tetrathionate under mild oxidizing conditions: 2 S2O32−→S4O62−+2e−2\,\mathrm{S_2O_3^{2-}} \rightarrow \mathrm{S_4O_6^{2-}} + 2e^-2S2​O32−​→S4​O62−​+2e− So here, A=S4O62−(tetrathionate ion)A = \mathrm{S_4O_6^{2-}} \quad \text{(tetrathionate ion)}A=S4​O62−​(tetrathionate ion)

  3. Now find the oxidation states of sulphur in S4O62−\mathrm{S_4O_6^{2-}}S4​O62−​.

    The structure of tetrathionate can be viewed as: −O3S−S−S−SO3−\mathrm{^-O_3S - S - S - SO_3^-}−O3​S−S−S−SO3−​ There are two kinds of sulphur atoms:

  • the two terminal sulphur atoms bonded to oxygen are each at oxidation state +5+5+5
  • the two inner sulphur atoms are each at oxidation state 000
  1. Check by average oxidation state method: Let average oxidation state of sulphur be xxx. Then, 4x+6(−2)=−24x + 6(-2) = -24x+6(−2)=−2 4x−12=−24x - 12 = -24x−12=−2 4x=104x = 104x=10 x=52x = \frac{5}{2}x=25​ This is only the average, not the oxidation state of each sulphur atom.

  2. Since the question asks for the oxidation state of sulphur in product AAA, and in tetrathionate sulphur exists in two oxidation states, the oxidized sulphur atoms are at +5+5+5.

Thus, the required oxidation state is: 5\boxed{5}5​

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