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D and F Block Elements question

2021 · 27 Aug · Shift 1 · Q19
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D and F Block Elements question

2021 · 27 Aug · Shift 1 · Q19

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
The number of f electrons in the ground state electronic configuration of Np (Z = 93) is ‾\underline{\hspace{2cm}}​. (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 18

  1. Write the ground-state configuration of neptunium, Np\mathrm{Np}Np (Z=93Z=93Z=93).

    After radon, the actinide filling begins. The ground-state electronic configuration of neptunium is: Np:[Rn] 5f46d17s2\mathrm{Np}: [\mathrm{Rn}]\,5f^4 6d^1 7s^2Np:[Rn]5f46d17s2

  2. Count all electrons present in f-subshells.

    The question asks for the number of fff electrons in the entire atom, not just valence electrons.

    • In the core [Rn][\mathrm{Rn}][Rn], the filled 4f4f4f subshell is present: 4f144f^{14}4f14
    • Outside the core, neptunium has: 5f45f^45f4

    Therefore, total number of fff electrons is: 14+4=1814 + 4 = 1814+4=18

  3. Final answer

    18\boxed{18}18​

  4. Comparison with stored answer

    Stored correct answer = 181818.

    My derived answer also is 181818, so they agree.

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