Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

D and F Block Elements question

2021 · 27 Aug · Shift 1 · Q8
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /D and F Block Elements
  5. /2021 · 27 Aug · Shift 1 · Q8

D and F Block Elements question

2021 · 27 Aug · Shift 1 · Q8

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The nature of oxides V2O3V_2O_3V2​O3​ and CrOCrOCrO is indexed as 'X' and 'Y' type respectively. The correct set of X and Y is :
  1. A
    X = basic Y = amphoteric
  2. B
    X = amphoteric Y = basic
  3. C
    X = acidic Y = acidic
  4. D
    X = basic Y = basic
View written solutionFree

Correct answer: D

  1. Identify the oxidation states
  • In V2O3V_2O_3V2​O3​: 2x+3(−2)=0 ⇒ 2x−6=0⇒x=+32x + 3(-2) = 0 \,\Rightarrow\, 2x - 6 = 0 \Rightarrow x = +32x+3(−2)=0⇒2x−6=0⇒x=+3 So this is vanadium(III) oxide.

  • In CrOCrOCrO: x+(−2)=0⇒x=+2x + (-2) = 0 \Rightarrow x = +2x+(−2)=0⇒x=+2 So this is chromium(II) oxide.

  1. Use the trend for transition metal oxides

For transition metals, oxides in lower oxidation states are generally basic, while oxides in higher oxidation states become amphoteric or acidic.

  1. Nature of V2O3V_2O_3V2​O3​
  • Vanadium is in the +3+3+3 oxidation state.
  • Lower oxidation state oxides of vanadium are generally basic.

Hence, X=basicX = \text{basic}X=basic

  1. Nature of CrOCrOCrO
  • Chromium is in the +2+2+2 oxidation state.
  • CrOCrOCrO is a basic oxide.

Hence, Y=basicY = \text{basic}Y=basic

  1. Match with the options
  • A: X=X=X= basic, Y=Y=Y= amphoteric →\to→ incorrect
  • B: X=X=X= amphoteric, Y=Y=Y= basic →\to→ incorrect
  • C: X=X=X= acidic, Y=Y=Y= acidic →\to→ incorrect
  • D: X=X=X= basic, Y=Y=Y= basic →\to→ correct

Final Answer

D\boxed{\text{D}}D​

PreviousNext

More from D and F Block Elements

  • The addition of dilute NaOH to Cr3+ salt solution will give :2021 · MCQ
  • Potassium permanganate on heating at 513 K gives a product which is :2021 · MCQ
  • In the structure of the dichromate ion, there is a :2021 · MCQ
  • Which one of the following lanthanides exhibits +2 oxidation state with diamagnetic nature? (Given Z for Nd = 60, Yb = 70, La = 57, Ce = 58)2021 · MCQ
  • The value of magnetic quantum number of the outermost electron of Zn+ ion is ​.2021 · Numerical
  • The Eu2+ ion is a strong reducing agent in spite of its ground state electronic configuration (outermost) : [Atomic number of Eu = 63]2021 · MCQ
  • In which one of the following sets all species show disproportionation reaction?2021 · MCQ
  • The incorrect statement is :2020 · MCQ