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D and F Block Elements question

2021 · 26 Feb · Shift 1 · Q7
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D and F Block Elements question

2021 · 26 Feb · Shift 1 · Q7

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Which one of the following lanthanoids does not form MO2MO_2MO2​? [M is lanthanoid metal]
  1. A
    Nd
  2. B
    Dy
  3. C
    Yb
  4. D
    Pr
View written solutionFree

Correct answer: C

  1. In lanthanoids, the dioxide formula MO2MO_2MO2​ corresponds to the metal being in the +4 oxidation state, because oxygen is −2-2−2 and M+2(−2)=0⇒M=+4.M + 2(-2)=0 \Rightarrow M=+4.M+2(−2)=0⇒M=+4.

  2. So the question reduces to: Which lanthanoid does not commonly show the +4 oxidation state?

  3. Among lanthanoids, the more stable +4 oxidation state is shown mainly by a few elements such as:

    • Ce: forms CeO2CeO_2CeO2​
    • Pr: can form PrO2PrO_2PrO2​
    • Tb: can form TbO2TbO_2TbO2​
    • Nd can also form dioxide under suitable conditions
  4. Now check the given options:

    • A: Nd — can form NdO2NdO_2NdO2​.
    • B: Dy — does not commonly form a stable dioxide DyO2DyO_2DyO2​.
    • C: Yb — does not form YbO2YbO_2YbO2​; however Yb is well known mainly for the +2 and +3 oxidation states.
    • D: Pr — forms PrO2PrO_2PrO2​.
  5. In standard JEE chemistry, the lanthanoids known to form dioxides are typically Ce, Pr, Tb, and Nd. Therefore among the given options, Yb is taken as the correct choice for not forming MO2MO_2MO2​.

  6. Hence, the correct answer is: C: Yb\boxed{\text{C: Yb}}C: Yb​

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