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D and F Block Elements question

2021 · 31 Aug · Shift 1 · Q5
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D and F Block Elements question

2021 · 31 Aug · Shift 1 · Q5

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Which one of the following lanthanides exhibits +2 oxidation state with diamagnetic nature? (Given Z for Nd = 60, Yb = 70, La = 57, Ce = 58)
  1. A
    Nd
  2. B
    Yb
  3. C
    La
  4. D
    Ce
View written solutionFree

Correct answer: B

  1. Find the electronic configurations of the given lanthanides

For lanthanides, the common configuration is based on xenon core, i.e. [Xe][Xe][Xe].

  • La(Z=57):[Xe]5d16s2\text{La} (Z=57): [Xe]5d^16s^2La(Z=57):[Xe]5d16s2
  • Ce(Z=58):[Xe]4f15d16s2\text{Ce} (Z=58): [Xe]4f^15d^16s^2Ce(Z=58):[Xe]4f15d16s2
  • Nd(Z=60):[Xe]4f46s2\text{Nd} (Z=60): [Xe]4f^46s^2Nd(Z=60):[Xe]4f46s2
  • Yb(Z=70):[Xe]4f146s2\text{Yb} (Z=70): [Xe]4f^{14}6s^2Yb(Z=70):[Xe]4f146s2
  1. Write the configurations in the +2+2+2 oxidation state

In the +2+2+2 state, two electrons are removed, generally from the 6s6s6s orbital first.

  • La2+:[Xe]5d1\text{La}^{2+}: [Xe]5d^1La2+:[Xe]5d1
  • Ce2+:[Xe]4f15d1\text{Ce}^{2+}: [Xe]4f^15d^1Ce2+:[Xe]4f15d1 (or effectively one unpaired electron remains in inner levels; in any case not diamagnetic)
  • Nd2+:[Xe]4f4\text{Nd}^{2+}: [Xe]4f^4Nd2+:[Xe]4f4
  • Yb2+:[Xe]4f14\text{Yb}^{2+}: [Xe]4f^{14}Yb2+:[Xe]4f14
  1. Check diamagnetic nature

A species is diamagnetic if all electrons are paired.

  • La2+\text{La}^{2+}La2+ has 5d15d^15d1 ⇒\Rightarrow⇒ paramagnetic
  • Ce2+\text{Ce}^{2+}Ce2+ has unpaired electron(s) ⇒\Rightarrow⇒ paramagnetic
  • Nd2+\text{Nd}^{2+}Nd2+ has 4f44f^44f4 ⇒\Rightarrow⇒ paramagnetic
  • Yb2+\text{Yb}^{2+}Yb2+ has 4f144f^{14}4f14, a completely filled fff-subshell ⇒\Rightarrow⇒ diamagnetic
  1. Identify the lanthanide showing stable +2+2+2 oxidation state with diamagnetic nature

Yb2+\text{Yb}^{2+}Yb2+ is especially stable because of the fully filled 4f144f^{14}4f14 configuration, and it is diamagnetic.

Therefore, the correct option is:

Yb\boxed{\text{Yb}}Yb​

So, Option B is correct.

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