JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Which one of the following lanthanides exhibits +2 oxidation state with diamagnetic nature? (Given Z for Nd = 60, Yb = 70, La = 57, Ce = 58)
- ANd
- BYb
- CLa
- DCe
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Correct answer: B
- Find the electronic configurations of the given lanthanides
For lanthanides, the common configuration is based on xenon core, i.e. .
- Write the configurations in the oxidation state
In the state, two electrons are removed, generally from the orbital first.
- (or effectively one unpaired electron remains in inner levels; in any case not diamagnetic)
- Check diamagnetic nature
A species is diamagnetic if all electrons are paired.
- has paramagnetic
- has unpaired electron(s) paramagnetic
- has paramagnetic
- has , a completely filled -subshell diamagnetic
- Identify the lanthanide showing stable oxidation state with diamagnetic nature
is especially stable because of the fully filled configuration, and it is diamagnetic.
Therefore, the correct option is:
So, Option B is correct.
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