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D and F Block Elements question

2021 · 27 Aug · Shift 2 · Q1
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D and F Block Elements question

2021 · 27 Aug · Shift 2 · Q1

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The addition of dilute NaOHNaOHNaOH to Cr3+Cr^{3+}Cr3+ salt solution will give :
  1. A
    a solution of [Cr(OH)4][Cr(OH)_4][Cr(OH)4​] −-−
  2. B
    precipitate of Cr2O3(H2O)nCr_2O_3(H_2O)_nCr2​O3​(H2​O)n​
  3. C
    precipitate of [Cr(OH)6][Cr(OH)_6][Cr(OH)6​]3 −-−
  4. D
    precipitate of Cr(OH)3Cr(OH)_3Cr(OH)3​
View written solutionFree

Correct answer: B

  1. Identify the reaction of Cr3+Cr^{3+}Cr3+ with dilute NaOHNaOHNaOH

When a salt solution containing Cr3+Cr^{3+}Cr3+ is treated with dilute NaOHNaOHNaOH, hydroxide ions are added to the aqueous chromium(III) ions.

Initially: Cr3++3OH−→Cr(OH)3↓Cr^{3+} + 3OH^- \rightarrow Cr(OH)_3 \downarrowCr3++3OH−→Cr(OH)3​↓

So a gelatinous precipitate is formed.

  1. Nature of the precipitate

In qualitative inorganic chemistry, the precipitated Cr(OH)3Cr(OH)_3Cr(OH)3​ is often represented more realistically as a hydrated oxide: Cr2O3⋅nH2OCr_2O_3\cdot nH_2OCr2​O3​⋅nH2​O

Thus, the precipitate obtained from adding dilute NaOHNaOHNaOH to Cr3+Cr^{3+}Cr3+ solution is commonly written as: Cr2O3(H2O)nCr_2O_3(H_2O)_nCr2​O3​(H2​O)n​

  1. Check the options
  • A: a solution of [Cr(OH)4]−[Cr(OH)_4]^-[Cr(OH)4​]−
    This is not obtained on adding only dilute NaOHNaOHNaOH. Chromium(III) hydroxide is amphoteric, but dissolution requires excess alkali.

  • B: precipitate of Cr2O3(H2O)nCr_2O_3(H_2O)_nCr2​O3​(H2​O)n​
    Correct. This is the hydrated form of precipitated chromium(III) hydroxide.

  • C: precipitate of [Cr(OH)6]3−[Cr(OH)_6]^{3-}[Cr(OH)6​]3−
    Incorrect. This is a complex ion, not a precipitate.

  • D: precipitate of Cr(OH)3Cr(OH)_3Cr(OH)3​
    Chemically this also describes the same precipitate, but in standard JEE-type treatment the precipitate is more specifically represented as hydrated chromium(III) oxide, i.e. Cr2O3(H2O)nCr_2O_3(H_2O)_nCr2​O3​(H2​O)n​.

  1. Final choice

Hence, the best answer is: B\boxed{B}B​

  1. Comparison with stored correct answer

Stored correct answer = B
Derived answer = B
So they agree.

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