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Heat and Thermodynamics question

2025 · 2 Apr · Shift 1 · Q72
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Heat and Thermodynamics question

2025 · 2 Apr · Shift 1 · Q72

JEE MainPhysicsHeat and ThermodynamicsNumerical+4 / −1
γA\gamma_{\mathrm{A}}γA​ is the specific heat ratio of monoatomic gas A having 3 translational degrees of freedom. γB\gamma_BγB​ is the specific heat ratio of polyatomic gas BBB having 3 translational, 3 rotational degrees of freedom and 1 vibrational mode. If γAγB=(1+1n)\frac{\gamma_A}{\gamma_B}=\left(1+\frac{1}{n}\right)γB​γA​​=(1+n1​), then the value of nnn is ‾\underline{\hspace{2cm}}​ .
Numerical answer
View written solutionFree

Correct answer: 3

  1. Specific heat ratio formula

For an ideal gas with total degrees of freedom fff, CV=f2R,CP=CV+R=f+22RC_V = \frac{f}{2}R, \qquad C_P = C_V + R = \frac{f+2}{2}RCV​=2f​R,CP​=CV​+R=2f+2​R Hence, γ=CPCV=f+2f\gamma = \frac{C_P}{C_V} = \frac{f+2}{f}γ=CV​CP​​=ff+2​

  1. For monoatomic gas AAA

A monoatomic gas has only 333 translational degrees of freedom. So, fA=3f_A = 3fA​=3 Therefore, γA=3+23=53\gamma_A = \frac{3+2}{3} = \frac{5}{3}γA​=33+2​=35​

  1. For polyatomic gas BBB

Given degrees of freedom:

  • 333 translational
  • 333 rotational
  • 111 vibrational mode

Now, one vibrational mode contributes 2 degrees of freedom (one kinetic + one potential). So total degrees of freedom: fB=3+3+2=8f_B = 3+3+2 = 8fB​=3+3+2=8 Thus, γB=8+28=108=54\gamma_B = \frac{8+2}{8} = \frac{10}{8} = \frac{5}{4}γB​=88+2​=810​=45​

  1. Compute the ratio

γAγB=5354=43\frac{\gamma_A}{\gamma_B} = \frac{\frac{5}{3}}{\frac{5}{4}} = \frac{4}{3}γB​γA​​=45​35​​=34​

Given, γAγB=1+1n\frac{\gamma_A}{\gamma_B} = 1 + \frac{1}{n}γB​γA​​=1+n1​ So, 1+1n=431 + \frac{1}{n} = \frac{4}{3}1+n1​=34​

Subtract 111 from both sides: 1n=43−1=13\frac{1}{n} = \frac{4}{3} - 1 = \frac{1}{3}n1​=34​−1=31​ Hence, n=3n=3n=3

  1. Comparison with stored answer

Derived answer is 333, which matches the stored correct answer.

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