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Heat and Thermodynamics question

2025 · 3 Apr · Shift 2 · Q56
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Heat and Thermodynamics question

2025 · 3 Apr · Shift 2 · Q56

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
An ideal gas exists in a state with pressure P0P_0P0​, volume V0V_0V0​. It is isothermally expanded to 4 times of its initial volume (V0)\left(\mathrm{V}_0\right)(V0​), then isobarically compressed to its original volume. Finally the system is heated isochorically to bring it to its initial state. The amount of heat exchanged in this process is
  1. A
    P0 V0(ln⁡2−0.75)\mathrm{P}_0 \mathrm{~V}_0(\ln 2-0.75)P0​ V0​(ln2−0.75)
  2. B
    P0 V0(2ln⁡2−0.75)\mathrm{P}_0 \mathrm{~V}_0(2 \ln 2-0.75)P0​ V0​(2ln2−0.75)
  3. C
    P0 V0(2ln⁡2−0.25)\mathrm{P}_0 \mathrm{~V}_0(2 \ln 2-0.25)P0​ V0​(2ln2−0.25)
  4. D
    P0 V0(ln⁡2−0.25)\mathrm{P}_0 \mathrm{~V}_0(\ln 2-0.25)P0​ V0​(ln2−0.25)
View written solutionFree

Correct answer: B

  1. Initial state

Let the initial state be A(P0,V0,T0)A(P_0,V_0,T_0)A(P0​,V0​,T0​).

For an ideal gas, P0V0=nRT0P_0V_0=nRT_0P0​V0​=nRT0​

The process consists of three steps:

  • A→BA \to BA→B: isothermal expansion from V0V_0V0​ to 4V04V_04V0​
  • B→CB \to CB→C: isobaric compression to volume V0V_0V0​
  • C→AC \to AC→A: isochoric heating back to the initial state

We need the net heat exchanged in the whole cyclic process.


  1. Step 1: Isothermal expansion A→BA \to BA→B

Since temperature is constant for an ideal gas, QAB=WAB=nRT0ln⁡(4V0V0)Q_{AB}=W_{AB}=nRT_0\ln\left(\frac{4V_0}{V_0}\right)QAB​=WAB​=nRT0​ln(V0​4V0​​) QAB=P0V0ln⁡4Q_{AB}=P_0V_0\ln 4QAB​=P0​V0​ln4 Using ln⁡4=2ln⁡2\ln 4=2\ln 2ln4=2ln2, QAB=2P0V0ln⁡2Q_{AB}=2P_0V_0\ln 2QAB​=2P0​V0​ln2

Also, at point BBB: PBVB=P0V0P_BV_B=P_0V_0PB​VB​=P0​V0​ with VB=4V0V_B=4V_0VB​=4V0​, so PB=P0V04V0=P04P_B=\frac{P_0V_0}{4V_0}=\frac{P_0}{4}PB​=4V0​P0​V0​​=4P0​​ Thus state BBB is (P04,4V0,T0)\left(\frac{P_0}{4},4V_0,T_0\right)(4P0​​,4V0​,T0​).


  1. Step 2: Isobaric compression B→CB \to CB→C

Pressure remains constant at P=P04P=\frac{P_0}{4}P=4P0​​ Volume changes from 4V04V_04V0​ to V0V_0V0​.

Work done by gas: WBC=P (VC−VB)=P04(V0−4V0)W_{BC}=P\,(V_C-V_B)=\frac{P_0}{4}(V_0-4V_0)WBC​=P(VC​−VB​)=4P0​​(V0​−4V0​) WBC=P04(−3V0)=−34P0V0W_{BC}=\frac{P_0}{4}(-3V_0)=-\frac{3}{4}P_0V_0WBC​=4P0​​(−3V0​)=−43​P0​V0​

Now find temperature at CCC: TC=PCVCnR=(P0/4)V0nR=T04T_C=\frac{P_CV_C}{nR}=\frac{(P_0/4)V_0}{nR}=\frac{T_0}{4}TC​=nRPC​VC​​=nR(P0​/4)V0​​=4T0​​ So, ΔTBC=TC−TB=T04−T0=−3T04\Delta T_{BC}=T_C-T_B=\frac{T_0}{4}-T_0=-\frac{3T_0}{4}ΔTBC​=TC​−TB​=4T0​​−T0​=−43T0​​

For an isobaric process, the heat is QBC=nCPΔTQ_{BC}=nC_P\Delta TQBC​=nCP​ΔT But since options are independent of gas type, it is easier to use the first law over the full cycle. Still, for this step alone, internal energy change depends on CVC_VCV​, so we avoid writing QBCQ_{BC}QBC​ explicitly.


  1. Step 3: Isochoric heating C→AC \to AC→A

Volume is constant at V0V_0V0​, so WCA=0W_{CA}=0WCA​=0 The system returns from TC=T0/4T_C=T_0/4TC​=T0​/4 to T0T_0T0​. Again, QCA=ΔUCAQ_{CA}=\Delta U_{CA}QCA​=ΔUCA​ depends on the gas type if treated separately.


  1. Use cyclic property

Since the gas returns to its initial state, over the complete cycle: ΔUcycle=0\Delta U_{\text{cycle}}=0ΔUcycle​=0 Hence, Qnet=WnetQ_{\text{net}}=W_{\text{net}}Qnet​=Wnet​

So we only need total work done by the gas.

Total work: Wnet=WAB+WBC+WCAW_{\text{net}}=W_{AB}+W_{BC}+W_{CA}Wnet​=WAB​+WBC​+WCA​ Wnet=2P0V0ln⁡2−34P0V0+0W_{\text{net}}=2P_0V_0\ln 2-\frac{3}{4}P_0V_0+0Wnet​=2P0​V0​ln2−43​P0​V0​+0 Wnet=P0V0(2ln⁡2−34)W_{\text{net}}=P_0V_0\left(2\ln 2-\frac{3}{4}\right)Wnet​=P0​V0​(2ln2−43​)

Therefore, Qnet=P0V0(2ln⁡2−0.75)Q_{\text{net}}=P_0V_0\left(2\ln 2-0.75\right)Qnet​=P0​V0​(2ln2−0.75)


  1. Compare with options

This matches:

Option B: P0V0(2ln⁡2−0.75)P_0V_0(2\ln 2-0.75)P0​V0​(2ln2−0.75)


  1. Verification with stored answer

Stored correct answer: B

Our derived answer: B

So they agree.

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