- AInternal energy of ice-water system remains unchanged.
- BPositive work is done by the ice-water system on the atmosphere.
- CPositive work is done on the ice-water system by the atmosphere.
- DInternal energy of the ice-water system decreases.
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Correct answer: C
- Process identification
A slab of ice melts at and at atmospheric pressure. This is a phase change from ice to water at constant temperature and constant external pressure.
- Use the first law of thermodynamics
For the system (ice + water), where is the work done by the system.
During melting, heat is absorbed as latent heat of fusion:
- Change in internal energy
Melting requires energy to weaken/break part of the intermolecular bonding structure of ice. Hence the internal energy increases: So:
- Option A (internal energy unchanged) is false.
- Option D (internal energy decreases) is false.
- Work done during melting
Ice has a larger volume than the same mass of water near . So when ice melts, the volume decreases:
At constant atmospheric pressure, work done by the system is Since , This means the system does negative work on the atmosphere, or equivalently, the atmosphere does positive work on the system.
Therefore:
- Option B is false.
- Option C is true.
- Final conclusion
The correct option is:
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