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Redox Reactions question

2024 · 30 Jan · Shift 1 · Q26
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Redox Reactions question

2024 · 30 Jan · Shift 1 · Q26

JEE MainChemistryRedox ReactionsNumerical+4 / −1
2MnO4−+bI−+cH2O→xI2+yMnO2+zO‾H2 \mathrm{MnO}_4^{-}+\mathrm{bI}^{-}+\mathrm{cH}_2 \mathrm{O} \rightarrow x \mathrm{I}_2+y \mathrm{MnO}_2+z \overline{\mathrm{O}} \mathrm{H}2MnO4−​+bI−+cH2​O→xI2​+yMnO2​+zOH If the above equation is balanced with integer coefficients, the value of zzz is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 8

  1. We need to balance:

2MnO4−+bI−+cH2O→xI2+yMnO2+zOH−2\mathrm{MnO_4^-} + b\mathrm{I^-} + c\mathrm{H_2O} \rightarrow x\mathrm{I_2} + y\mathrm{MnO_2} + z\mathrm{OH^-}2MnO4−​+bI−+cH2​O→xI2​+yMnO2​+zOH−

Since there are already 222 permanganate ions on the left, let us balance Mn first.

  1. Balance manganese:

Each MnO4−\mathrm{MnO_4^-}MnO4−​ gives one Mn atom, so total Mn on left = 222. Thus,

y=2y = 2y=2

So the equation becomes

2MnO4−+bI−+cH2O→xI2+2MnO2+zOH−2\mathrm{MnO_4^-} + b\mathrm{I^-} + c\mathrm{H_2O} \rightarrow x\mathrm{I_2} + 2\mathrm{MnO_2} + z\mathrm{OH^-}2MnO4−​+bI−+cH2​O→xI2​+2MnO2​+zOH−

  1. This is a redox reaction in basic medium, so use half-reactions.

Oxidation half-reaction

Iodide is oxidized to iodine:

2I−→I2+2e−2\mathrm{I^-} \rightarrow \mathrm{I_2} + 2e^-2I−→I2​+2e−

Reduction half-reaction

Permanganate is reduced to MnO2\mathrm{MnO_2}MnO2​ in basic medium. Start in acidic form:

MnO4−+4H++3e−→MnO2+2H2O\mathrm{MnO_4^-} + 4\mathrm{H^+} + 3e^- \rightarrow \mathrm{MnO_2} + 2\mathrm{H_2O}MnO4−​+4H++3e−→MnO2​+2H2​O

Convert to basic medium by adding 4OH−4\mathrm{OH^-}4OH− to both sides:

MnO4−+4H++4OH−+3e−→MnO2+2H2O+4OH−\mathrm{MnO_4^-} + 4\mathrm{H^+} + 4\mathrm{OH^-} + 3e^- \rightarrow \mathrm{MnO_2} + 2\mathrm{H_2O} + 4\mathrm{OH^-}MnO4−​+4H++4OH−+3e−→MnO2​+2H2​O+4OH−

Since H++OH−=H2O\mathrm{H^+} + \mathrm{OH^-} = \mathrm{H_2O}H++OH−=H2​O,

MnO4−+4H2O+3e−→MnO2+2H2O+4OH−\mathrm{MnO_4^-} + 4\mathrm{H_2O} + 3e^- \rightarrow \mathrm{MnO_2} + 2\mathrm{H_2O} + 4\mathrm{OH^-}MnO4−​+4H2​O+3e−→MnO2​+2H2​O+4OH−

Cancel 2H2O2\mathrm{H_2O}2H2​O from both sides:

MnO4−+2H2O+3e−→MnO2+4OH−\mathrm{MnO_4^-} + 2\mathrm{H_2O} + 3e^- \rightarrow \mathrm{MnO_2} + 4\mathrm{OH^-}MnO4−​+2H2​O+3e−→MnO2​+4OH−

  1. Since there are 2MnO4−2\mathrm{MnO_4^-}2MnO4−​, multiply the reduction half-reaction by 222:

2MnO4−+4H2O+6e−→2MnO2+8OH−2\mathrm{MnO_4^-} + 4\mathrm{H_2O} + 6e^- \rightarrow 2\mathrm{MnO_2} + 8\mathrm{OH^-}2MnO4−​+4H2​O+6e−→2MnO2​+8OH−

  1. To balance electrons, multiply the oxidation half-reaction by 333:

6I−→3I2+6e−6\mathrm{I^-} \rightarrow 3\mathrm{I_2} + 6e^-6I−→3I2​+6e−

  1. Add the two half-reactions:

2MnO4−+4H2O+6I−→2MnO2+8OH−+3I22\mathrm{MnO_4^-} + 4\mathrm{H_2O} + 6\mathrm{I^-} \rightarrow 2\mathrm{MnO_2} + 8\mathrm{OH^-} + 3\mathrm{I_2}2MnO4−​+4H2​O+6I−→2MnO2​+8OH−+3I2​

Rewriting in the given form:

2MnO4−+6I−+4H2O→3I2+2MnO2+8OH−2\mathrm{MnO_4^-} + 6\mathrm{I^-} + 4\mathrm{H_2O} \rightarrow 3\mathrm{I_2} + 2\mathrm{MnO_2} + 8\mathrm{OH^-}2MnO4−​+6I−+4H2​O→3I2​+2MnO2​+8OH−

  1. Therefore,

z=8z = 8z=8

  1. Comparison with stored correct answer:

Stored correct answer = 888

Our derived answer = 888

Hence, the answer agrees.

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