JEE MainChemistryRedox ReactionsNumerical+4 / −1
Number of moles of ions required by of to oxidise oxalate ion to is .
Numerical answer
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Correct answer: 8
- Write the relevant half-reaction for permanganate in acidic medium
In acidic medium, permanganate is reduced as:
This shows that 1 mole of requires 8 moles of for its reduction.
- Write the oxidation half-reaction for oxalate ion
Oxalate ion is oxidised to carbon dioxide as:
- Balance electrons
To match electrons, multiply the oxalate half-reaction by 5 and the permanganate half-reaction by 2 if writing the full reaction. But the question asks only for the number of moles of required by 1 mole of .
From the permanganate half-reaction directly:
- Check with full balanced reaction
The full balanced reaction in acidic medium is:
So, per mole of :
Thus, the number of moles of required is 8.
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