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Redox Reactions question

2023 · 8 Apr · Shift 1 · Q5
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  5. /2023 · 8 Apr · Shift 1 · Q5

Redox Reactions question

2023 · 8 Apr · Shift 1 · Q5

JEE MainChemistryRedox ReactionsMCQ+4 / −1
2IO3−+xI−+12H+→6I2+6H2O2 \mathrm{IO}_{3}^{-}+x \mathrm{I}^{-}+12 \mathrm{H}^{+} \rightarrow 6 \mathrm{I}_{2}+6 \mathrm{H}_{2} \mathrm{O}2IO3−​+xI−+12H+→6I2​+6H2​O What is the value of xxx ?
  1. A
    10
  2. B
    2
  3. C
    12
  4. D
    6
View written solutionFree

Correct answer: A

  1. We need to balance the redox equation:

2IO3−+xI−+12H+→6I2+6H2O2\mathrm{IO_3^-} + x\mathrm{I^-} + 12\mathrm{H^+} \rightarrow 6\mathrm{I_2} + 6\mathrm{H_2O}2IO3−​+xI−+12H+→6I2​+6H2​O

We must find the value of xxx.

  1. Check iodine atoms on the right side:

6I26\mathrm{I_2}6I2​ contains 6×2=126 \times 2 = 126×2=12 iodine atoms.

  1. Count iodine atoms on the left side:
  • From 2IO3−2\mathrm{IO_3^-}2IO3−​, iodine atoms = 222
  • From xI−x\mathrm{I^-}xI−, iodine atoms = xxx

So total iodine atoms on the left =

2+x2 + x2+x

  1. Equate iodine atoms on both sides:

2+x=122 + x = 122+x=12

x=10x = 10x=10

  1. Quick charge check: Left side charge:
  • 2IO3−⇒−22\mathrm{IO_3^-} \Rightarrow -22IO3−​⇒−2
  • 10I−⇒−1010\mathrm{I^-} \Rightarrow -1010I−⇒−10
  • 12H+⇒+1212\mathrm{H^+} \Rightarrow +1212H+⇒+12

Net charge:

−2−10+12=0-2 -10 +12 = 0−2−10+12=0

Right side is neutral: 6I2+6H2O6\mathrm{I_2} + 6\mathrm{H_2O}6I2​+6H2​O So the equation is charge balanced as well.

  1. Therefore, the correct value is:

10\boxed{10}10​

So the correct option is A.

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