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Redox Reactions question

2023 · 6 Apr · Shift 1 · Q5
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  5. /2023 · 6 Apr · Shift 1 · Q5

Redox Reactions question

2023 · 6 Apr · Shift 1 · Q5

JEE MainChemistryRedox ReactionsMCQ+4 / −1
Which of the following options are correct for the reaction 2[Au(CN)2]−(aq)+Zn(s)→2Au(s)+[Zn(CN)4]2−(aq)2\left[\mathrm{Au}(\mathrm{CN})_{2}\right]^{-}(\mathrm{aq})+\mathrm{Zn}(\mathrm{s}) \rightarrow 2 \mathrm{Au}(\mathrm{s})+\left[\mathrm{Zn}(\mathrm{CN})_{4}\right]^{2-}(\mathrm{aq})2[Au(CN)2​]−(aq)+Zn(s)→2Au(s)+[Zn(CN)4​]2−(aq) A. Redox reaction B. Displacement reaction C. Decomposition reaction D. Combination reaction Choose the correct answer from the options given below:
  1. A
    A and B only
  2. B
    C and D only
  3. C
    A only
  4. D
    A and D only
View written solutionFree

Correct answer: A

  1. Write the given reaction

2[Au(CN)2]−(aq)+Zn(s)→2Au(s)+[Zn(CN)4]2−(aq)2[\mathrm{Au}(\mathrm{CN})_2]^- (aq) + \mathrm{Zn}(s) \rightarrow 2\mathrm{Au}(s) + [\mathrm{Zn}(\mathrm{CN})_4]^{2-}(aq)2[Au(CN)2​]−(aq)+Zn(s)→2Au(s)+[Zn(CN)4​]2−(aq)

We need to identify which type(s) of reaction it is.


  1. Check whether it is a redox reaction

Let us determine oxidation states of the metals.

For gold in [Au(CN)2]−[\mathrm{Au}(\mathrm{CN})_2]^-[Au(CN)2​]−

Each CN−\mathrm{CN}^-CN− ligand has charge −1-1−1.

Let oxidation state of Au be xxx.

x+2(−1)=−1x + 2(-1) = -1x+2(−1)=−1 x−2=−1x - 2 = -1x−2=−1 x=+1x = +1x=+1

So, Au is in the +1+1+1 oxidation state initially.

In the product, gold is:

Au(s)=0\mathrm{Au}(s) = 0Au(s)=0

Thus, Au goes from +1+1+1 to 000, so Au is reduced.

For zinc

Initially:

Zn(s)=0\mathrm{Zn}(s) = 0Zn(s)=0

In [Zn(CN)4]2−[\mathrm{Zn}(\mathrm{CN})_4]^{2-}[Zn(CN)4​]2−, let oxidation state of Zn be yyy:

y+4(−1)=−2y + 4(-1) = -2y+4(−1)=−2 y−4=−2y - 4 = -2y−4=−2 y=+2y = +2y=+2

So, Zn goes from 000 to +2+2+2, so Zn is oxidized.

Since oxidation and reduction both occur, this is a redox reaction.

So, A is correct.


  1. Check whether it is a displacement reaction

Zinc displaces gold from its complex ion:

  • Zn enters the complex form as [Zn(CN)4]2−[\mathrm{Zn}(\mathrm{CN})_4]^{2-}[Zn(CN)4​]2−
  • Au is released as elemental gold

This is essentially a displacement reaction, specifically a metal displacement based on relative reactivity.

So, B is correct.


  1. Check whether it is a decomposition reaction

A decomposition reaction involves one compound breaking into simpler substances.

Here, two reactants are involved:

[Au(CN)2]− and Zn[\mathrm{Au}(\mathrm{CN})_2]^- \text{ and } \mathrm{Zn}[Au(CN)2​]− and Zn

So this is not a decomposition reaction.

Thus, C is incorrect.


  1. Check whether it is a combination reaction

A combination reaction involves two or more reactants combining to form a single product.

Here, products are:

2Au(s) and [Zn(CN)4]2−2\mathrm{Au}(s) \text{ and } [\mathrm{Zn}(\mathrm{CN})_4]^{2-}2Au(s) and [Zn(CN)4​]2−

There is not a single combined product, so this is not a combination reaction.

Thus, D is incorrect.


  1. Conclusion

Correct statements are:

  • A. Redox reaction ✔️
  • B. Displacement reaction ✔️
  • C. Decomposition reaction ✖️
  • D. Combination reaction ✖️

Hence, the correct option is:

A: A and B only\boxed{\text{A: A and B only}}A: A and B only​

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