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Electrochemistry question

2023 · 25 Jan · Shift 2 · Q17
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  5. /2023 · 25 Jan · Shift 2 · Q17

Electrochemistry question

2023 · 25 Jan · Shift 2 · Q17

JEE MainChemistryElectrochemistryNumerical+4 / −1
Pt(s)∣H2(g)(1 bar)∣H+(aq)(1 M)∣∣M3+(aq),M+(aq)∣Pt(s)Pt(s)|{H_2}(g)(1\,bar)|{H^ + }(aq)(1\,M)||{M^{3 + }}(aq),{M^ + }(aq)|Pt(s)Pt(s)∣H2​(g)(1bar)∣H+(aq)(1M)∣∣M3+(aq),M+(aq)∣Pt(s) The Ecell\mathrm{E_{cell}}Ecell​ for the given cell is 0.1115 V at 298 K when [M+(aq)][M3+(aq)]=10a{{\left[ {{M^ + }(aq)} \right]} \over {\left[ {{M^{3 + }}(aq)} \right]}} = {10^a}[M3+(aq)][M+(aq)]​=10a The value of aaa is ‾\underline{\hspace{2cm}}​ Given : EM3+/M+θ=0.2\mathrm{E_{{M^{3 + }}/{M^ + }}^\theta = 0.2}EM3+/M+θ​=0.2 V 2.303RTF=0.059V{{2.303RT} \over F} = 0.059VF2.303RT​=0.059V
Numerical answer
View written solutionFree

Correct answer: 3

  1. Identify the half-cells

The cell is

Pt(s)∣H2(g,1 bar)∣H+(aq,1 M)∣∣M3+(aq),M+(aq)∣Pt(s)Pt(s)|H_2(g,1\,bar)|H^+(aq,1\,M)||M^{3+}(aq),M^+(aq)|Pt(s)Pt(s)∣H2​(g,1bar)∣H+(aq,1M)∣∣M3+(aq),M+(aq)∣Pt(s)

Left electrode is the standard hydrogen electrode, so Eleft=EH+/H2∘=0 VE_{\text{left}} = E^\circ_{H^+/H_2} = 0\,\text{V}Eleft​=EH+/H2​∘​=0V

Right electrode involves the couple: M3++2e−→M+M^{3+} + 2e^- \rightarrow M^+M3++2e−→M+ with EM3+/M+∘=0.2 VE^\circ_{M^{3+}/M^+} = 0.2\,\text{V}EM3+/M+∘​=0.2V

Since the hydrogen electrode is on the left and the metal ion electrode is on the right, Ecell=Eright−Eleft=ErightE_{\text{cell}} = E_{\text{right}} - E_{\text{left}} = E_{\text{right}}Ecell​=Eright​−Eleft​=Eright​ Thus, Eright=0.1115 VE_{\text{right}} = 0.1115\,\text{V}Eright​=0.1115V


  1. Apply Nernst equation to the right electrode

For the reduction reaction M3++2e−→M+M^{3+} + 2e^- \rightarrow M^+M3++2e−→M+

The reaction quotient is Q=[M+][M3+]Q = \frac{[M^+]}{[M^{3+}]}Q=[M3+][M+]​

So the Nernst equation is

E=E∘−0.0592log⁡[M+][M3+]E = E^\circ - \frac{0.059}{2}\log \frac{[M^+]}{[M^{3+}]}E=E∘−20.059​log[M3+][M+]​

Given [M+][M3+]=10a\frac{[M^+]}{[M^{3+}]} = 10^a[M3+][M+]​=10a so

Hence,

E=0.2−0.0592aE = 0.2 - \frac{0.059}{2}aE=0.2−20.059​a

But given E=0.1115 VE = 0.1115\,\text{V}E=0.1115V Therefore,

0.1115=0.2−0.0592a0.1115 = 0.2 - \frac{0.059}{2}a0.1115=0.2−20.059​a
  1. Solve for aaa
0.2−0.1115=0.0592a0.2 - 0.1115 = \frac{0.059}{2}a0.2−0.1115=20.059​a 0.0885=0.0295 a0.0885 = 0.0295\,a0.0885=0.0295a a=0.08850.0295=3a = \frac{0.0885}{0.0295} = 3a=0.02950.0885​=3
  1. Final answer
3\boxed{3}3​
  1. Comparison with stored correct answer

Stored correct answer = 3

Our derived answer = 3

So the answer matches.

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