Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Electrochemistry question

2023 · 31 Jan · Shift 2 · Q19
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Electrochemistry
  5. /2023 · 31 Jan · Shift 2 · Q19

Electrochemistry question

2023 · 31 Jan · Shift 2 · Q19

JEE MainChemistryElectrochemistryNumerical+4 / −1
The resistivity of a 0.8M0.8 \mathrm{M}0.8M solution of an electrolyte is 5×10−3Ω cm5 \times 10^{-3} \Omega~ \mathrm{cm}5×10−3Ω cm. Its molar conductivity is ‾×104 Ω−1 cm2 mol−1\underline{\hspace{2cm}}\times 10^{4}~ \Omega^{-1} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}​×104 Ω−1 cm2 mol−1. (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 25

  1. Given data

    • Concentration: C=0.8 M=0.8 mol L−1C = 0.8\,\text{M} = 0.8\,\text{mol L}^{-1}C=0.8M=0.8mol L−1
    • Resistivity: ρ=5×10−3 Ω cm\rho = 5 \times 10^{-3}\,\Omega\,\text{cm}ρ=5×10−3Ωcm
  2. Find conductivity

    Conductivity is the reciprocal of resistivity: κ=1ρ=15×10−3=200 Ω−1cm−1\kappa = \frac{1}{\rho} = \frac{1}{5\times 10^{-3}} = 200\,\Omega^{-1}\text{cm}^{-1}κ=ρ1​=5×10−31​=200Ω−1cm−1

  3. Use formula for molar conductivity

    Λm=κ×1000C\Lambda_m = \kappa \times \frac{1000}{C}Λm​=κ×C1000​

    Substituting values: Λm=200×10000.8\Lambda_m = 200 \times \frac{1000}{0.8}Λm​=200×0.81000​

    Λm=200×1250=250000 Ω−1cm2mol−1\Lambda_m = 200 \times 1250 = 250000\,\Omega^{-1}\text{cm}^2\text{mol}^{-1}Λm​=200×1250=250000Ω−1cm2mol−1

  4. Match with required format

    We need to write: Λm=‾×104 Ω−1cm2mol−1\Lambda_m = \underline{\hspace{1cm}} \times 10^4\,\Omega^{-1}\text{cm}^2\text{mol}^{-1}Λm​=​×104Ω−1cm2mol−1

    Since 250000=25×104250000 = 25 \times 10^4250000=25×104

    the required integer is: 25\boxed{25}25​

  5. Comparison with stored answer

    Stored correct answer = 252525

    This matches our derived answer.

PreviousNext

More from Electrochemistry

  • The cell potential for the following cell Pt |H2​(g)|H+ (aq)|| Cu2+ (0.01 M)|Cu(s) is 0.576 V at 298 K. The pH of the solution is ​. (Nearest integer) (Given : ECu2+/Cuo​=0.34 V and F2.303RT​=0.06…2022 · Numerical
  • The resistance of a conductivity cell containing 0.01 M KCl solution at 298 K is 1750 Ω. If the conductivity of 0.01 M KCl solution at 298 K is 0.152 × 10 − 3 S cm − 1, then the cell constant of the conductivity cell is ​×…2022 · Numerical
  • The cell potential for Zn​Zn2+(aq)​​Snx+​Sn is 0.801 V at 298 K. The reaction quotient for the above reaction is 10−2. The number of…2022 · Numerical
  • The spin-only magnetic moment value of M3+ ion (in gaseous state) from the pairs Cr3+ / Cr2+, Mn3+ / Mn2+, Fe3+ / Fe2+ and Co3+ / Co2+ that has negative standard electrode potential, is ​…2022 · Numerical
  • The molar conductivity of a conductivity cell filled with 10 moles of 20 mL NaCl solution is Λm1​ and that of 20 moles another identical cell heaving 80 mL NaCl solution is Λm2​. The conductivities exhibited by…2022 · MCQ
  • In a cell, the following reactions take place Fe2+→Fe3++e−2I−→I2​+2e−​EFe3+/Fe2+o​=0.77VEI2​/I−o​=0.54V​…2022 · Numerical
  • A solution of Fe2​(SO4​)3​ is electrolyzed for 'x' min with a current of 1.5 A to deposit 0.3482 g of Fe. The value of x is ​. [nearest integer] Given : 1 F = 96500 C mol − 1 Atomic mass of Fe = 56 g mol…2022 · Numerical
  • The correct order of reduction potentials of the following pairs is A. Cl2​/Cl− B. I2​/I− C. Ag+/Ag D. Na+/Na E. Li+/Li Choose the correct answer from the options given below.2022 · MCQ