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Electrochemistry question

2023 · 25 Jan · Shift 1 · Q16
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  5. /2023 · 25 Jan · Shift 1 · Q16

Electrochemistry question

2023 · 25 Jan · Shift 1 · Q16

JEE MainChemistryElectrochemistryNumerical+4 / −1
Consider the cell Pt(s)∣H2(g) (1 atm)∣H+ (aq,[H+]=1)∣∣Fe3+(aq),Fe2+(aq)∣Pt(s)\mathrm{Pt(s)|{H_2}(g)\,(1\,atm)|{H^ + }\,(aq,[{H^ + }] = 1)||F{e^{3 + }}(aq),F{e^{2 + }}(aq)|Pt(s)}Pt(s)∣H2​(g)(1atm)∣H+(aq,[H+]=1)∣∣Fe3+(aq),Fe2+(aq)∣Pt(s) Given EFe3+/Fe2+o=0.771 V\mathrm{E_{F{e^{3 + }}/F{e^{2 + }}}^o = 0.771\,V}EFe3+/Fe2+o​=0.771V and EH+/1/2 H2o=0 V, T=298 K\mathrm{E_{{H^ + }/1/2\,{H_2}}^o = 0\,V,\,T = 298\,K}EH+/1/2H2​o​=0V,T=298K If the potential of the cell is 0.712 V, the ratio of concentration of Fe 2+^{2+}2+ to Fe 3+^{3+}3+ is ‾\underline{\hspace{2cm}}​ (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 10

  1. Identify the half-cells

The cell is: Pt(s)∣H2(g,1 atm)∣H+(aq,[H+]=1)∣∣Fe3+(aq),Fe2+(aq)∣Pt(s)\mathrm{Pt(s)|H_2(g,1\,atm)|H^+(aq, [H^+]=1)||Fe^{3+}(aq),Fe^{2+}(aq)|Pt(s)}Pt(s)∣H2​(g,1atm)∣H+(aq,[H+]=1)∣∣Fe3+(aq),Fe2+(aq)∣Pt(s)

Left electrode is the hydrogen electrode: 2H++2e−⇌H2\mathrm{2H^+ + 2e^- \rightleftharpoons H_2}2H++2e−⇌H2​ Since [H+]=1[\mathrm{H^+}] = 1[H+]=1 and PH2=1 atmP_{H_2}=1\,\text{atm}PH2​​=1atm, it is under standard conditions, so Eleft=0 VE_{\text{left}} = 0\,\text{V}Eleft​=0V

Right electrode is: Fe3++e−⇌Fe2+\mathrm{Fe^{3+} + e^- \rightleftharpoons Fe^{2+}}Fe3++e−⇌Fe2+ with EFe3+/Fe2+∘=0.771 VE^\circ_{\mathrm{Fe^{3+}/Fe^{2+}}} = 0.771\,\text{V}EFe3+/Fe2+∘​=0.771V

  1. Write the Nernst equation for the iron electrode

For the reduction Fe3++e−→Fe2+\mathrm{Fe^{3+} + e^- \rightarrow Fe^{2+}}Fe3++e−→Fe2+ we have n=1n=1n=1, so EFe=EFe∘−0.05911log⁡[Fe2+][Fe3+]E_{\mathrm{Fe}} = E^\circ_{\mathrm{Fe}} - \frac{0.0591}{1}\log\frac{[\mathrm{Fe^{2+}}]}{[\mathrm{Fe^{3+}}]}EFe​=EFe∘​−10.0591​log[Fe3+][Fe2+]​ Thus, EFe=0.771−0.0591log⁡[Fe2+][Fe3+]E_{\mathrm{Fe}} = 0.771 - 0.0591\log\frac{[\mathrm{Fe^{2+}}]}{[\mathrm{Fe^{3+}}]}EFe​=0.771−0.0591log[Fe3+][Fe2+]​

  1. Use the cell potential expression

Since the right electrode has higher reduction potential, it acts as cathode. The hydrogen electrode is the anode.

Therefore, Ecell=Ecathode−Eanode=EFe−EHE_{\text{cell}} = E_{\text{cathode}} - E_{\text{anode}} = E_{\mathrm{Fe}} - E_{\mathrm{H}}Ecell​=Ecathode​−Eanode​=EFe​−EH​ But EH=0E_{\mathrm{H}}=0EH​=0, so Ecell=EFeE_{\text{cell}} = E_{\mathrm{Fe}}Ecell​=EFe​ Given: Ecell=0.712 VE_{\text{cell}} = 0.712\,\text{V}Ecell​=0.712V Hence, 0.712=0.771−0.0591log⁡[Fe2+][Fe3+]0.712 = 0.771 - 0.0591\log\frac{[\mathrm{Fe^{2+}}]}{[\mathrm{Fe^{3+}}]}0.712=0.771−0.0591log[Fe3+][Fe2+]​

  1. Solve for the ratio

Rearranging, 0.0591log⁡[Fe2+][Fe3+]=0.771−0.712=0.0590.0591\log\frac{[\mathrm{Fe^{2+}}]}{[\mathrm{Fe^{3+}}]} = 0.771 - 0.712 = 0.0590.0591log[Fe3+][Fe2+]​=0.771−0.712=0.059 So, log⁡[Fe2+][Fe3+]=0.0590.0591≈0.998≈1\log\frac{[\mathrm{Fe^{2+}}]}{[\mathrm{Fe^{3+}}]} = \frac{0.059}{0.0591} \approx 0.998 \approx 1log[Fe3+][Fe2+]​=0.05910.059​≈0.998≈1 Therefore, [Fe2+][Fe3+]≈101=10\frac{[\mathrm{Fe^{2+}}]}{[\mathrm{Fe^{3+}}]} \approx 10^1 = 10[Fe3+][Fe2+]​≈101=10

  1. Nearest integer

10\boxed{10}10​

  1. Comparison with stored answer

Stored correct answer = 101010.

Our derived answer matches the stored answer.

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