JEE MainChemistryElectrochemistryNumerical+4 / −1
Consider the cell Given and If the potential of the cell is 0.712 V, the ratio of concentration of Fe to Fe is (Nearest integer)
Numerical answer
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Correct answer: 10
- Identify the half-cells
The cell is:
Left electrode is the hydrogen electrode: Since and , it is under standard conditions, so
Right electrode is: with
- Write the Nernst equation for the iron electrode
For the reduction we have , so Thus,
- Use the cell potential expression
Since the right electrode has higher reduction potential, it acts as cathode. The hydrogen electrode is the anode.
Therefore, But , so Given: Hence,
- Solve for the ratio
Rearranging, So, Therefore,
- Nearest integer
- Comparison with stored answer
Stored correct answer = .
Our derived answer matches the stored answer.
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