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Electrochemistry question

2023 · 31 Jan · Shift 1 · Q17
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Electrochemistry question

2023 · 31 Jan · Shift 1 · Q17

JEE MainChemistryElectrochemistryNumerical+4 / −1
The logarithm of equilibrium constant for the reaction Pd2++4Cl−⇌PdCl42−\mathrm{Pd}^{2+}+4 \mathrm{Cl}^{-} \rightleftharpoons \mathrm{PdCl}_{4}^{2-}Pd2++4Cl−⇌PdCl42−​ is ‾\underline{\hspace{2cm}}​ (Nearest integer) Given : 2.303R T F=0.06 VPd(aq)2++2e−⇌Pd(s)E⊖=0.83 VPdCl42−(aq)+2e−⇌Pd(s)+4Cl−(aq)E⊖=0.65 V\frac{2.303 R \mathrm{~T}}{\mathrm{~F}}=0.06 \mathrm{~V} \mathrm{Pd}_{(\mathrm{aq})}^{2+}+2 \mathrm{e}^{-} \rightleftharpoons \mathrm{Pd}(\mathrm{s}) \quad \mathrm{E}^{\ominus}=0.83 \mathrm{~V} \begin{aligned} & \mathrm{PdCl}_{4}^{2-}(\mathrm{aq})+2 \mathrm{e}^{-} \rightleftharpoons \mathrm{Pd}(\mathrm{s})+4 \mathrm{Cl}^{-}(\mathrm{aq}) \mathrm{E}^{\ominus}=0.65 \mathrm{~V} \end{aligned} F2.303R T​=0.06 VPd(aq)2+​+2e−⇌Pd(s)E⊖=0.83 V​PdCl42−​(aq)+2e−⇌Pd(s)+4Cl−(aq)E⊖=0.65 V​
Numerical answer
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