- AIn manganate and permanganate ions, the p-bonding takes place by overlap of p-orbitals of oxygen and d-orbitals of manganese
- BManganate ion is green in colour and permanganate ion in purple in colour
- CManganate and permanganate ions are paramagnetic
- DManganate and permanganate ions are tetrahedral
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Correct answer: C
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Identify the species and oxidation states
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In manganate ion, : So Mn is in oxidation state .
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In permanganate ion, : So Mn is in oxidation state .
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Check magnetic nature
Mn has atomic number :
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For : remove electrons from and from : This has one unpaired electron, so is paramagnetic.
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For : remove electrons from and from : This has no unpaired electrons, so is diamagnetic.
Therefore, the statement "Manganate and permanganate ions are paramagnetic" is incorrect, because only manganate is paramagnetic, while permanganate is diamagnetic.
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Check the other statements
Option A: In standard JEE-level inorganic chemistry, the -bonding in oxoanions such as manganate and permanganate is described as overlap of filled -orbitals of oxygen with vacant -orbitals of manganese ( bonding). So this statement is taken as correct.
Option B:
- is green
- is purple/violet
Hence, correct.
Option D: Both and have four bonding pairs around Mn and no lone pair on the central atom, so both are tetrahedral. Hence, correct.
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Conclusion
The incorrect statement is:
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