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D and F Block Elements question

2020 · 3 Sep · Shift 2 · Q7
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D and F Block Elements question

2020 · 3 Sep · Shift 2 · Q7

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The incorrect statement is :
  1. A
    In manganate and permanganate ions, the p-bonding takes place by overlap of p-orbitals of oxygen and d-orbitals of manganese
  2. B
    Manganate ion is green in colour and permanganate ion in purple in colour
  3. C
    Manganate and permanganate ions are paramagnetic
  4. D
    Manganate and permanganate ions are tetrahedral
View written solutionFree

Correct answer: C

  1. Identify the species and oxidation states

    • In manganate ion, MnO42−\mathrm{MnO_4^{2-}}MnO42−​: x+4(−2)=−2⇒x=+6x + 4(-2) = -2 \Rightarrow x = +6x+4(−2)=−2⇒x=+6 So Mn is in oxidation state +6+6+6.

    • In permanganate ion, MnO4−\mathrm{MnO_4^-}MnO4−​: x+4(−2)=−1⇒x=+7x + 4(-2) = -1 \Rightarrow x = +7x+4(−2)=−1⇒x=+7 So Mn is in oxidation state +7+7+7.

  2. Check magnetic nature

    Mn has atomic number 252525: Mn=[Ar]3d54s2\mathrm{Mn} = [Ar]3d^5 4s^2Mn=[Ar]3d54s2

    • For Mn6+\mathrm{Mn^{6+}}Mn6+: remove 222 electrons from 4s4s4s and 444 from 3d3d3d: Mn6+=[Ar]3d1\mathrm{Mn^{6+}} = [Ar]3d^1Mn6+=[Ar]3d1 This has one unpaired electron, so MnO42−\mathrm{MnO_4^{2-}}MnO42−​ is paramagnetic.

    • For Mn7+\mathrm{Mn^{7+}}Mn7+: remove 222 electrons from 4s4s4s and 555 from 3d3d3d: Mn7+=[Ar]3d0\mathrm{Mn^{7+}} = [Ar]3d^0Mn7+=[Ar]3d0 This has no unpaired electrons, so MnO4−\mathrm{MnO_4^-}MnO4−​ is diamagnetic.

    Therefore, the statement "Manganate and permanganate ions are paramagnetic" is incorrect, because only manganate is paramagnetic, while permanganate is diamagnetic.

  3. Check the other statements

    Option A: In standard JEE-level inorganic chemistry, the π\piπ-bonding in oxoanions such as manganate and permanganate is described as overlap of filled ppp-orbitals of oxygen with vacant ddd-orbitals of manganese (pπ−dπp\pi-d\pipπ−dπ bonding). So this statement is taken as correct.

    Option B:

    • MnO42−\mathrm{MnO_4^{2-}}MnO42−​ is green
    • MnO4−\mathrm{MnO_4^-}MnO4−​ is purple/violet

    Hence, correct.

    Option D: Both MnO42−\mathrm{MnO_4^{2-}}MnO42−​ and MnO4−\mathrm{MnO_4^-}MnO4−​ have four bonding pairs around Mn and no lone pair on the central atom, so both are tetrahedral. Hence, correct.

  4. Conclusion

    The incorrect statement is: C\boxed{\text{C}}C​

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