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D and F Block Elements question

2021 · 26 Aug · Shift 1 · Q17
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D and F Block Elements question

2021 · 26 Aug · Shift 1 · Q17

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
The number of 4f electrons in the ground statement electronic configuration of Gd2+Gd^{2+}Gd2+ is ‾\underline{\hspace{2cm}}​. [Atomic number of Gd = 64]
Numerical answer
View written solutionFree

Correct answer: 7

  1. Write the ground-state electronic configuration of neutral Gd

Gadolinium has atomic number 646464. Its ground-state configuration is:

Gd=[Xe] 4f75d16s2\mathrm{Gd} = [Xe] \, 4f^7 5d^1 6s^2Gd=[Xe]4f75d16s2

This is a well-known exceptional configuration due to the extra stability of half-filled 4f74f^74f7.

  1. Form Gd2+\mathrm{Gd}^{2+}Gd2+ by removing two electrons

When forming cations, electrons are removed first from the outermost shell (highest principal quantum number).

For Gd:

  • 6s6s6s electrons are removed first.

So,

Gd2+=[Xe] 4f75d1\mathrm{Gd}^{2+} = [Xe] \, 4f^7 5d^1Gd2+=[Xe]4f75d1

  1. Count the number of 4f4f4f electrons

From

Gd2+=[Xe] 4f75d1\mathrm{Gd}^{2+} = [Xe] \, 4f^7 5d^1Gd2+=[Xe]4f75d1

the number of electrons in the 4f4f4f subshell is

777

  1. Final answer

The number of 4f4f4f electrons in Gd2+\mathrm{Gd}^{2+}Gd2+ is:

7\boxed{7}7​

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