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D and F Block Elements question

2021 · 25 Jul · Shift 2 · Q18
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D and F Block Elements question

2021 · 25 Jul · Shift 2 · Q18

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
Number of electrons present in 4f orbital of Ho3+Ho^{3+}Ho3+ ion is ‾\underline{\hspace{2cm}}​. (Given Atomic No. of Ho = 67)
Numerical answer
View written solutionFree

Correct answer: 10

  1. Write the electronic configuration of neutral Ho

Holmium has atomic number 676767.

So, the electronic configuration of HoHoHo is: [Xe] 4f116s2[Xe] \, 4f^{11} 6s^2[Xe]4f116s2

  1. Form the Ho3+Ho^{3+}Ho3+ ion

To form Ho3+Ho^{3+}Ho3+, remove 333 electrons from the neutral atom.

In lanthanides, electrons are removed first from 6s6s6s and then from 4f4f4f.

So:

  • Remove 222 electrons from 6s2→6s06s^2 \rightarrow 6s^06s2→6s0
  • Remove 111 electron from 4f11→4f104f^{11} \rightarrow 4f^{10}4f11→4f10

Thus, Ho3+=[Xe] 4f10Ho^{3+} = [Xe] \, 4f^{10}Ho3+=[Xe]4f10

  1. Count electrons in the 4f4f4f orbital/subshell

The configuration 4f104f^{10}4f10 means there are 101010 electrons in the 4f4f4f subshell.

Therefore, the number of electrons present in 4f4f4f of Ho3+Ho^{3+}Ho3+ is: 10\boxed{10}10​

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