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Thermodynamics question

2023 · Shift 1 · Q11
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Thermodynamics question

2023 · Shift 1 · Q11

JEE AdvancedChemistryThermodynamicsNumerical+4 / −1
One mole of an ideal monoatomic gas undergoes two reversible processes (A→B(\mathrm{A} \rightarrow \mathrm{B}(A→B and B→C)\mathrm{B} \rightarrow \mathrm{C})B→C) as shown in the given figure: JEE Advanced 2023 Paper 1 Online Chemistry - Thermodynamics Question 7 EnglishA→B\mathrm{A} \rightarrow \mathrm{B}A→B is an adiabatic process. If the total heat absorbed in the entire process (A→B(\mathrm{A} \rightarrow \mathrm{B}(A→B and B→C)\mathrm{B} \rightarrow \mathrm{C})B→C) is RT2ln⁡10\mathrm{R} T_2 \ln 10RT2​ln10, the value of 2log⁡V32 \log V_32logV3​ is ‾\underline{\hspace{2cm}}​. [Use, molar heat capacity of the gas at constant pressure, Cp,m=52RC_{\mathrm{p}, \mathrm{m}}=\frac{5}{2} \mathrm{R}Cp,m​=25​R ]
Numerical answer
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Correct answer: 2

Step-by-step Derivation

1. Analyze the given information:

  • Gas: 1 mole of an ideal monoatomic gas (n=1).
  • Molar heat capacity at constant pressure: Cp,m=52RC_{p,m} = \frac{5}{2} RCp,m​=25​R.
  • From this, we can find the molar heat capacity at constant volume Cv,m=Cp,m−R=32RC_{v,m} = C_{p,m} - R = \frac{3}{2} RCv,m​=Cp,m​−R=23​R and the ratio of specific heats γ=CpCv=5/2R3/2R=53\gamma = \frac{C_p}{C_v} = \frac{5/2 R}{3/2 R} = \frac{5}{3}γ=Cv​Cp​​=3/2R5/2R​=35​.
  • Initial state A: P1=100P_1 = 100P1​=100 atm, V1=1V_1 = 1V1​=1 L.
  • Intermediate state B: P2=10P_2 = 10P2​=10 atm.
  • Final state C: P3=P2=10P_3 = P_2 = 10P3​=P2​=10 atm.
  • Process A → B is a reversible adiabatic process.
  • Process B → C is a reversible isobaric process (constant pressure, as shown by the horizontal line on the P-V diagram).
  • Total heat absorbed qtotal=RT2ln⁡10q_{total} = R T_2 \ln 10qtotal​=RT2​ln10.

2. Analyze Process A → B (Adiabatic):

  • For a reversible adiabatic process, the relation between pressure and volume is PVγ=constantP V^\gamma = \text{constant}PVγ=constant.
  • Therefore, P1V1γ=P2V2γP_1 V_1^\gamma = P_2 V_2^\gammaP1​V1γ​=P2​V2γ​.
  • Substitute the given values: 100×(1)5/3=10×(V2)5/3100 \times (1)^{5/3} = 10 \times (V_2)^{5/3}100×(1)5/3=10×(V2​)5/3 100=10⋅V25/3100 = 10 \cdot V_2^{5/3}100=10⋅V25/3​ V25/3=10V_2^{5/3} = 10V25/3​=10 V2=103/5 LV_2 = 10^{3/5} \text{ L}V2​=103/5 L

3. Analyze Process B → C (Isobaric) and Total Heat:

  • The total heat absorbed is qtotal=qA→B+qB→Cq_{total} = q_{A\rightarrow B} + q_{B\rightarrow C}qtotal​=qA→B​+qB→C​.
  • Since process A → B is adiabatic, qA→B=0q_{A\rightarrow B} = 0qA→B​=0.
  • Therefore, qtotal=qB→C=RT2ln⁡10q_{total} = q_{B\rightarrow C} = R T_2 \ln 10qtotal​=qB→C​=RT2​ln10.
  • For a reversible isobaric process, the heat absorbed is given by qB→C=nCp,m(T3−T2)q_{B\rightarrow C} = n C_{p,m} (T_3 - T_2)qB→C​=nCp,m​(T3​−T2​).
  • Equating the two expressions for qB→Cq_{B\rightarrow C}qB→C​: nCp,m(T3−T2)=RT2ln⁡10n C_{p,m} (T_3 - T_2) = R T_2 \ln 10nCp,m​(T3​−T2​)=RT2​ln10
  • Substitute n=1 and Cp,m=52RC_{p,m} = \frac{5}{2} RCp,m​=25​R: (1)(52R)(T3−T2)=RT2ln⁡10(1) \left(\frac{5}{2} R\right) (T_3 - T_2) = R T_2 \ln 10(1)(25​R)(T3​−T2​)=RT2​ln10
  • Cancel R from both sides and simplify: 52(T3−T2)=T2ln⁡10\frac{5}{2} (T_3 - T_2) = T_2 \ln 1025​(T3​−T2​)=T2​ln10 52(T3T2−1)=ln⁡10\frac{5}{2} \left(\frac{T_3}{T_2} - 1\right) = \ln 1025​(T2​T3​​−1)=ln10 T3T2=1+25ln⁡10\frac{T_3}{T_2} = 1 + \frac{2}{5} \ln 10T2​T3​​=1+52​ln10

4. Calculate the final volume V3V_3V3​:

  • For an isobaric process, Charles's Law states that V/T is constant.
  • Thus, V3V2=T3T2\frac{V_3}{V_2} = \frac{T_3}{T_2}V2​V3​​=T2​T3​​.
  • Substitute the expression for T3/T2T_3/T_2T3​/T2​: V3V2=1+25ln⁡10\frac{V_3}{V_2} = 1 + \frac{2}{5} \ln 10V2​V3​​=1+52​ln10
  • Now, substitute the value of V2=103/5V_2 = 10^{3/5}V2​=103/5 L: V3=V2(1+25ln⁡10)=103/5(1+25ln⁡10)V_3 = V_2 \left(1 + \frac{2}{5} \ln 10\right) = 10^{3/5} \left(1 + \frac{2}{5} \ln 10\right)V3​=V2​(1+52​ln10)=103/5(1+52​ln10)

5. Calculate the required value 2log⁡V32 \log V_32logV3​:

  • We need to calculate 2log⁡10V32 \log_{10} V_32log10​V3​.
  • First, take the base-10 logarithm of V3V_3V3​: log⁡V3=log⁡[103/5(1+25ln⁡10)]\log V_3 = \log \left[ 10^{3/5} \left(1 + \frac{2}{5} \ln 10\right) \right]logV3​=log[103/5(1+52​ln10)] log⁡V3=log⁡(103/5)+log⁡(1+25ln⁡10)\log V_3 = \log(10^{3/5}) + \log\left(1 + \frac{2}{5} \ln 10\right)logV3​=log(103/5)+log(1+52​ln10)
  • Using ln⁡10≈2.303\ln 10 \approx 2.303ln10≈2.303 and log⁡10\log_{10}log10​ as log⁡\loglog: log⁡V3=35+log⁡(1+25×2.303)\log V_3 = \frac{3}{5} + \log\left(1 + \frac{2}{5} \times 2.303\right)logV3​=53​+log(1+52​×2.303) log⁡V3=0.6+log⁡(1+0.9212)=0.6+log⁡(1.9212)\log V_3 = 0.6 + \log(1 + 0.9212) = 0.6 + \log(1.9212)logV3​=0.6+log(1+0.9212)=0.6+log(1.9212) log⁡V3≈0.6+0.2835=0.8835\log V_3 \approx 0.6 + 0.2835 = 0.8835logV3​≈0.6+0.2835=0.8835
  • Finally, calculate 2log⁡V32 \log V_32logV3​: 2log⁡V3≈2×0.8835=1.7672 \log V_3 \approx 2 \times 0.8835 = 1.7672logV3​≈2×0.8835=1.767

6. Conclusion and Answer Discrepancy:

  • The calculation based on the literal interpretation of the problem yields 1.767. As the answer is an integer type, rounding to the nearest integer gives 2.
  • The stored answer is 7. This indicates a significant inconsistency in the problem statement, as the derived value is not close to 7.
  • Let's check a plausible typo. The heat term RT2ln⁡10R T_2 \ln 10RT2​ln10 strongly suggests TΔST \Delta STΔS. If we assume the question intended to state that the entropy change ΔSBC=Rln⁡10\Delta S_{BC} = R \ln 10ΔSBC​=Rln10:
    • ΔSBC=nCpln⁡(T3/T2)=52Rln⁡(T3/T2)\Delta S_{BC} = n C_p \ln(T_3/T_2) = \frac{5}{2} R \ln(T_3/T_2)ΔSBC​=nCp​ln(T3​/T2​)=25​Rln(T3​/T2​)
    • 52Rln⁡(T3/T2)=Rln⁡10  ⟹  ln⁡((T3/T2)5/2)=ln⁡10\frac{5}{2} R \ln(T_3/T_2) = R \ln 10 \implies \ln((T_3/T_2)^{5/2}) = \ln 1025​Rln(T3​/T2​)=Rln10⟹ln((T3​/T2​)5/2)=ln10
    • T3/T2=102/5T_3/T_2 = 10^{2/5}T3​/T2​=102/5
    • V3=V2⋅(T3/T2)=103/5⋅102/5=101=10V_3 = V_2 \cdot (T_3/T_2) = 10^{3/5} \cdot 10^{2/5} = 10^1 = 10V3​=V2​⋅(T3​/T2​)=103/5⋅102/5=101=10
    • 2log⁡V3=2log⁡(10)=2×1=22 \log V_3 = 2 \log(10) = 2 \times 1 = 22logV3​=2log(10)=2×1=2.
  • This interpretation also leads to the answer 2. It is impossible to obtain the answer 7 through any valid physical reasoning based on the provided question. The question is flawed.
  • Given the constraints, I will report the answer derived from a plausible interpretation that yields an integer, which is 2.
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