JEE AdvancedChemistryThermodynamicsNumerical+4 / −1
One mole of an ideal monoatomic gas undergoes two reversible processes and as shown in the given figure:
is an adiabatic process. If the total heat absorbed in the entire process and is , the value of is . [Use, molar heat capacity of the gas at constant pressure, ]
is an adiabatic process. If the total heat absorbed in the entire process and is , the value of is . [Use, molar heat capacity of the gas at constant pressure, ]Numerical answer
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Correct answer: 2
Step-by-step Derivation
1. Analyze the given information:
- Gas: 1 mole of an ideal monoatomic gas (
n=1). - Molar heat capacity at constant pressure: .
- From this, we can find the molar heat capacity at constant volume and the ratio of specific heats .
- Initial state A: atm, L.
- Intermediate state B: atm.
- Final state C: atm.
- Process A → B is a reversible adiabatic process.
- Process B → C is a reversible isobaric process (constant pressure, as shown by the horizontal line on the P-V diagram).
- Total heat absorbed .
2. Analyze Process A → B (Adiabatic):
- For a reversible adiabatic process, the relation between pressure and volume is .
- Therefore, .
- Substitute the given values:
3. Analyze Process B → C (Isobaric) and Total Heat:
- The total heat absorbed is .
- Since process A → B is adiabatic, .
- Therefore, .
- For a reversible isobaric process, the heat absorbed is given by .
- Equating the two expressions for :
- Substitute
n=1and : - Cancel
Rfrom both sides and simplify:
4. Calculate the final volume :
- For an isobaric process, Charles's Law states that
V/Tis constant. - Thus, .
- Substitute the expression for :
- Now, substitute the value of L:
5. Calculate the required value :
- We need to calculate .
- First, take the base-10 logarithm of :
- Using and as :
- Finally, calculate :
6. Conclusion and Answer Discrepancy:
- The calculation based on the literal interpretation of the problem yields
1.767. As the answer is an integer type, rounding to the nearest integer gives2. - The stored answer is
7. This indicates a significant inconsistency in the problem statement, as the derived value is not close to7. - Let's check a plausible typo. The heat term strongly suggests . If we assume the question intended to state that the entropy change :
- .
- This interpretation also leads to the answer
2. It is impossible to obtain the answer7through any valid physical reasoning based on the provided question. The question is flawed. - Given the constraints, I will report the answer derived from a plausible interpretation that yields an integer, which is
2.
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