JEE AdvancedChemistryThermodynamicsMultiple correct+4 / −2
An ideal gas undergoes a reversible isothermal expansion from state I to state II followed by a reversible adiabatic expansion from state II to state III. The correct plot(s) representing the changes from state I to state III is (are) (p : pressure, V : volume, T : temperature, H : enthalpy, S : entropy)
- A

- B

- C

- D

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Correct answer: A, B, D
- Process I II: reversible isothermal expansion
For an ideal gas in an isothermal process, So during :
- increases
- decreases
- remains constant
- For an ideal gas, enthalpy depends only on temperature, so hence remains constant.
- Entropy increases because reversible isothermal expansion gives
- Process II III: reversible adiabatic expansion
For a reversible adiabatic process of an ideal gas, During expansion:
- increases
- decreases
- decreases
- Since depends only on for an ideal gas, so decreases.
- For a reversible adiabatic process, Therefore entropy remains constant from state II to III.
- Net change from I to III
Combining both steps:
- Volume: increases throughout.
- Pressure: decreases throughout.
- Temperature: constant first, then decreases. Hence from I to III, final temperature is lower than initial temperature.
- Enthalpy: constant first, then decreases. So final enthalpy is lower than initial enthalpy.
- Entropy: increases in the isothermal step, then remains constant in the adiabatic step. Thus
- Shape/plot conclusions
From the above behavior:
- In a vs plot, first an isotherm, then a steeper adiabatic curve. This is correct.
- In a vs plot, first horizontal (isothermal), then decreasing curve (adiabatic). This is correct.
- In an vs plot, first horizontal to the right (since constant, increases), then vertical downward (since constant, decreases). This is correct.
- Any plot showing entropy decreasing, or enthalpy increasing, or temperature remaining constant in the adiabatic step would be incorrect.
Therefore the correct options are:
- Comparison with stored answer
Stored correct answer:
My derived answer matches the stored answer exactly.
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