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Thermodynamics question

2021 · Shift 1 · Q14
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Thermodynamics question

2021 · Shift 1 · Q14

JEE AdvancedChemistryThermodynamicsMultiple correct+4 / −2
An ideal gas undergoes a reversible isothermal expansion from state I to state II followed by a reversible adiabatic expansion from state II to state III. The correct plot(s) representing the changes from state I to state III is (are) (p : pressure, V : volume, T : temperature, H : enthalpy, S : entropy)
  1. A
    JEE Advanced 2021 Paper 1 Online Chemistry - Thermodynamics Question 21 English Option 1
  2. B
    JEE Advanced 2021 Paper 1 Online Chemistry - Thermodynamics Question 21 English Option 2
  3. C
    JEE Advanced 2021 Paper 1 Online Chemistry - Thermodynamics Question 21 English Option 3
  4. D
    JEE Advanced 2021 Paper 1 Online Chemistry - Thermodynamics Question 21 English Option 4
View written solutionFree

Correct answer: A, B, D

  1. Process I →\to→ II: reversible isothermal expansion

For an ideal gas in an isothermal process, T=constant,pV=constantT=\text{constant}, \qquad pV=\text{constant}T=constant,pV=constant So during I→III \to III→II:

  • VVV increases
  • ppp decreases
  • TTT remains constant
  • For an ideal gas, enthalpy depends only on temperature, so H=H(T)H=H(T)H=H(T) hence HHH remains constant.
  • Entropy increases because reversible isothermal expansion gives ΔS=nRln⁡V2V1>0\Delta S = nR\ln\frac{V_2}{V_1}>0ΔS=nRlnV1​V2​​>0
  1. Process II →\to→ III: reversible adiabatic expansion

For a reversible adiabatic process of an ideal gas, q=0,pVγ=constant,TVγ−1=constantq=0, \qquad pV^\gamma=\text{constant}, \qquad TV^{\gamma-1}=\text{constant}q=0,pVγ=constant,TVγ−1=constant During expansion:

  • VVV increases
  • ppp decreases
  • TTT decreases
  • Since HHH depends only on TTT for an ideal gas, H=nCpTH=nC_pTH=nCp​T so HHH decreases.
  • For a reversible adiabatic process, ΔS=0\Delta S=0ΔS=0 Therefore entropy remains constant from state II to III.
  1. Net change from I to III

Combining both steps:

  • Volume: increases throughout.
  • Pressure: decreases throughout.
  • Temperature: constant first, then decreases. Hence from I to III, final temperature is lower than initial temperature.
  • Enthalpy: constant first, then decreases. So final enthalpy is lower than initial enthalpy.
  • Entropy: increases in the isothermal step, then remains constant in the adiabatic step. Thus S3>S1S_3>S_1S3​>S1​
  1. Shape/plot conclusions

From the above behavior:

  • In a ppp vs VVV plot, first an isotherm, then a steeper adiabatic curve. This is correct.
  • In a TTT vs VVV plot, first horizontal (isothermal), then decreasing curve (adiabatic). This is correct.
  • In an HHH vs SSS plot, first horizontal to the right (since HHH constant, SSS increases), then vertical downward (since SSS constant, HHH decreases). This is correct.
  • Any plot showing entropy decreasing, or enthalpy increasing, or temperature remaining constant in the adiabatic step would be incorrect.

Therefore the correct options are: A, B, D\boxed{A,\ B,\ D}A, B, D​

  1. Comparison with stored answer

Stored correct answer: A,B,DA, B, DA,B,D

My derived answer matches the stored answer exactly.

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