JEE AdvancedChemistryThermodynamicsNumerical+2 / −1
For the reaction, X(s) Y(s) + Z(g), the plot of versus is given below (in solid line), where pz is the pressure (in bar) of the gas Z at temperature T and = 1 bar.
(Given, , where the equilibrium constant, and the gas constant, R = 8.314 J K 1 mol 1)The value of standard enthalpy, Ho (in kJ mol 1) for the given reaction is .
(Given, , where the equilibrium constant, and the gas constant, R = 8.314 J K 1 mol 1)The value of standard enthalpy, Ho (in kJ mol 1) for the given reaction is .Numerical answer
View written solutionFree
Correct answer: 166.28
- Given relation
For the equilibrium we are given and
So, if we know the slope of the graph of versus , we can find .
- Graph variable transformation
The graph is plotted against
Hence,
Therefore,
So if the slope of the given graph of vs is , then
Thus,
- Read slope from the graph
From the straight line (solid line), the slope is negative and equals approximately
So,
Converting to kJ mol,
- Final answer
- Comparison with stored answer
Stored correct answer = 166.28
My derived answer matches the stored answer.
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