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Thermodynamics question

2021 · Shift 1 · Q7
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Thermodynamics question

2021 · Shift 1 · Q7

JEE AdvancedChemistryThermodynamicsNumerical+2 / −1
For the reaction, X(s) ⇌\rightleftharpoons⇌ Y(s) + Z(g), the plot of ln⁡pzpθ\ln {{pz} \over {{p^\theta }}}lnpθpz​ versus 104T{{{{10}^4}} \over T}T104​ is given below (in solid line), where pz is the pressure (in bar) of the gas Z at temperature T and pθ{{p^\theta }}pθ = 1 bar. JEE Advanced 2021 Paper 1 Online Chemistry - Thermodynamics Question 20 English Comprehension (Given, d(ln⁡K)d(1T)=−ΔHθR{{d(\ln K)} \over {d\left( {{1 \over T}} \right)}} = - {{\Delta {H^\theta }} \over R}d(T1​)d(lnK)​=−RΔHθ​, where the equilibrium constant, K=pzpθK = {{pz} \over {{p^\theta }}}K=pθpz​ and the gas constant, R = 8.314 J K −-− 1 mol −-− 1)The value of standard enthalpy, Δ\DeltaΔ Ho (in kJ mol −-− 1) for the given reaction is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 166.28

  1. Given relation

For the equilibrium X(s)⇌Y(s)+Z(g),X(s) \rightleftharpoons Y(s) + Z(g),X(s)⇌Y(s)+Z(g), we are given K=pZpθK = \frac{p_Z}{p^\theta}K=pθpZ​​ and d(ln⁡K)d(1/T)=−ΔH∘R.\frac{d(\ln K)}{d(1/T)} = -\frac{\Delta H^\circ}{R}.d(1/T)d(lnK)​=−RΔH∘​.

So, if we know the slope of the graph of ln⁡(pZ/pθ)\ln(p_Z/p^\theta)ln(pZ​/pθ) versus 1/T1/T1/T, we can find ΔH∘\Delta H^\circΔH∘.


  1. Graph variable transformation

The graph is plotted against x=104T.x = \frac{10^4}{T}.x=T104​.

Hence, 1T=x104.\frac{1}{T} = \frac{x}{10^4}.T1​=104x​.

Therefore, d(ln⁡K)d(1/T)=d(ln⁡K)d(x/104)=104 d(ln⁡K)dx.\frac{d(\ln K)}{d(1/T)} = \frac{d(\ln K)}{d(x/10^4)} = 10^4\,\frac{d(\ln K)}{dx}.d(1/T)d(lnK)​=d(x/104)d(lnK)​=104dxd(lnK)​.

So if the slope of the given graph of ln⁡K\ln KlnK vs 104/T10^4/T104/T is mmm, then d(ln⁡K)d(1/T)=104m.\frac{d(\ln K)}{d(1/T)} = 10^4 m.d(1/T)d(lnK)​=104m.

Thus, −ΔH∘R=104m-\frac{\Delta H^\circ}{R} = 10^4 m−RΔH∘​=104m ⇒ΔH∘=−R (104m).\Rightarrow \Delta H^\circ = -R\,(10^4 m).⇒ΔH∘=−R(104m).


  1. Read slope from the graph

From the straight line (solid line), the slope is negative and equals approximately m=−2.0.m = -2.0.m=−2.0.

So, ΔH∘=−8.314×104×(−2.0)  J mol−1.\Delta H^\circ = -8.314 \times 10^4 \times (-2.0)\;\text{J mol}^{-1}.ΔH∘=−8.314×104×(−2.0)J mol−1.

ΔH∘=1.6628×105  J mol−1.\Delta H^\circ = 1.6628 \times 10^5\;\text{J mol}^{-1}.ΔH∘=1.6628×105J mol−1.

Converting to kJ mol−1^{-1}−1, ΔH∘=166.28  kJ mol−1.\Delta H^\circ = 166.28\;\text{kJ mol}^{-1}.ΔH∘=166.28kJ mol−1.


  1. Final answer

166.28\boxed{166.28}166.28​


  1. Comparison with stored answer

Stored correct answer = 166.28

My derived answer matches the stored answer.

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