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Thermodynamics question

2022 · Shift 1 · Q1
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Thermodynamics question

2022 · Shift 1 · Q1

JEE AdvancedChemistryThermodynamicsNumerical+3 / −1
2 mol of Hg(g)2 \mathrm{~mol} \,\mathrm{of}\, \mathrm{Hg}(\mathrm{g})2 molofHg(g) is combusted in a fixed volume bomb calorimeter with excess of O2\mathrm{O}_{2}O2​ at 298 K298 \mathrm{~K}298 K and 1 atm into HgO(s)\mathrm{HgO}(s)HgO(s). During the reaction, temperature increases from 298.0 K298.0 \mathrm{~K}298.0 K to 312.8 K312.8 \mathrm{~K}312.8 K. If heat capacity of the bomb calorimeter and enthalpy of formation of Hg(g)\mathrm{Hg}(g)Hg(g) are 20.00 kJ K−120.00 \mathrm{~kJ} \mathrm{~K}^{-1}20.00 kJ K−1 and 61.32 kJmol−161.32 \mathrm{~kJ}\mathrm{mol}^{-1}61.32 kJmol−1 at 298 K298 \mathrm{~K}298 K, respectively, the calculated standard molar enthalpy of formation of HgO(s)\mathrm{HgO}(s)HgO(s) at 298 K\mathrm{K}K is X kJ mol−1\mathrm{X}\, \mathrm{kJ}\, \mathrm{mol}^{-1}XkJmol−1. The value of ∣X∣|\mathrm{X}|∣X∣ is ‾\underline{\hspace{2cm}}​ . [Given: Gas constant R=8.3 J K−1 mol−1\mathrm{R}=8.3 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}R=8.3 J K−1 mol−1 ]
Numerical answer
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