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Heat and Thermodynamics question

2002 · Shift 0 · Q152
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Heat and Thermodynamics question

2002 · Shift 0 · Q152

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
1 mole of a gas with γ=7/5\gamma = 7/5γ=7/5 is mixed with 111 mole of a gas with γ=5/3,\gamma = 5/3,γ=5/3, then the value of γ\gammaγ for the resulting mixture is
  1. A
    7/57/57/5
  2. B
    2/52/52/5
  3. C
    3/23/23/2
  4. D
    12/712/712/7
View written solutionFree

Correct answer: C

  1. For each gas, use γ=CpCv,Cp−Cv=R\gamma = \frac{C_p}{C_v}, \qquad C_p - C_v = Rγ=Cv​Cp​​,Cp​−Cv​=R Hence, Cv=Rγ−1,Cp=γRγ−1C_v = \frac{R}{\gamma - 1}, \qquad C_p = \frac{\gamma R}{\gamma - 1}Cv​=γ−1R​,Cp​=γ−1γR​

  2. For gas 1, given γ1=75\gamma_1 = \frac{7}{5}γ1​=57​ So, Cv1=R75−1=R25=5R2C_{v1} = \frac{R}{\frac{7}{5}-1} = \frac{R}{\frac{2}{5}} = \frac{5R}{2}Cv1​=57​−1R​=52​R​=25R​ Cp1=Cv1+R=5R2+R=7R2C_{p1} = C_{v1}+R = \frac{5R}{2}+R = \frac{7R}{2}Cp1​=Cv1​+R=25R​+R=27R​

  3. For gas 2, given γ2=53\gamma_2 = \frac{5}{3}γ2​=35​ So, Cv2=R53−1=R23=3R2C_{v2} = \frac{R}{\frac{5}{3}-1} = \frac{R}{\frac{2}{3}} = \frac{3R}{2}Cv2​=35​−1R​=32​R​=23R​ Cp2=Cv2+R=3R2+R=5R2C_{p2} = C_{v2}+R = \frac{3R}{2}+R = \frac{5R}{2}Cp2​=Cv2​+R=23R​+R=25R​

  4. Since 1 mole of each gas is mixed, total heat capacities of the mixture are additive: Cv(mix)=Cv1+Cv2=5R2+3R2=4RC_v^{(\text{mix})} = C_{v1}+C_{v2} = \frac{5R}{2}+\frac{3R}{2} = 4RCv(mix)​=Cv1​+Cv2​=25R​+23R​=4R Cp(mix)=Cp1+Cp2=7R2+5R2=6RC_p^{(\text{mix})} = C_{p1}+C_{p2} = \frac{7R}{2}+\frac{5R}{2} = 6RCp(mix)​=Cp1​+Cp2​=27R​+25R​=6R

  5. Therefore, for the mixture, γmix=Cp(mix)Cv(mix)=6R4R=32\gamma_{\text{mix}} = \frac{C_p^{(\text{mix})}}{C_v^{(\text{mix})}} = \frac{6R}{4R} = \frac{3}{2}γmix​=Cv(mix)​Cp(mix)​​=4R6R​=23​

  6. Checking options:

    • A: 75\frac{7}{5}57​ ❌
    • B: 25\frac{2}{5}52​ ❌
    • C: 32\frac{3}{2}23​ ✅
    • D: 127\frac{12}{7}712​ ❌

Hence the correct answer is Option C.

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