Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Structure of Atom question

2025 · 7 Apr · Shift 1 · Q14
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Structure of Atom
  5. /2025 · 7 Apr · Shift 1 · Q14

Structure of Atom question

2025 · 7 Apr · Shift 1 · Q14

JEE MainChemistryStructure of AtomMCQ+4 / −1
JEE Main 2025 (Online) 7th April Morning Shift Chemistry - Structure of Atom Question 6 English Which of the following statements are correct, if the threshold frequency of caesium is 5.16×1014 Hz5.16 \times10^{14} \mathrm{~Hz}5.16×1014 Hz ? A. When Cs is placed inside a vacuum chamber with an ammeter connected to it and yellow light is focused on Cs , the ammeter shows the presence of current. B. When the brightness of the yellow light is dimmed, the value of the current in the ammeter is reduced. C. When a red light is used instead of the yellow light, the current produced is higher with respect to the yellow light. D. When a blue light is used, the ammeter shows the formation of current. E. When a white light is used. the ammeter shows formation of current. Choose the correct answer from the options given below:
  1. A
    B, C and D Only
  2. B
    A, C, D and E Only
  3. C
    A, B, D and E Only
  4. D
    A, D and E Only
View written solutionFree

Correct answer: C

  1. Use the photoelectric condition

For photoelectric emission to occur,

ν≥ν0\nu \ge \nu_0ν≥ν0​

where ν0=5.16×1014 Hz\nu_0 = 5.16 \times 10^{14}\,\text{Hz}ν0​=5.16×1014Hz is the threshold frequency of cesium.

If incident light has frequency less than threshold, no electrons are emitted, so no current is detected.


  1. Compare common visible-light frequencies with the threshold

Using

ν=cλ\nu = \frac{c}{\lambda}ν=λc​

with c=3×108 m/sc = 3 \times 10^8\,\text{m/s}c=3×108m/s.

Typical wavelengths:

  • Red light: λ≈650\lambda \approx 650λ≈650 to 700 nm700\,\text{nm}700nm
  • Yellow light: λ≈580 nm\lambda \approx 580\,\text{nm}λ≈580nm
  • Blue light: λ≈450 nm\lambda \approx 450\,\text{nm}λ≈450nm
  • White light: mixture of all visible frequencies

Now estimate frequencies:

  • Yellow light (λ≈580 nm\lambda \approx 580\,\text{nm}λ≈580nm):
νy=3×108580×10−9≈5.17×1014 Hz\nu_y = \frac{3\times 10^8}{580\times 10^{-9}} \approx 5.17\times 10^{14}\,\text{Hz}νy​=580×10−93×108​≈5.17×1014Hz

So,

νy>ν0\nu_y > \nu_0νy​>ν0​

Hence yellow light can eject electrons.

  • Red light (λ≈650 nm\lambda \approx 650\,\text{nm}λ≈650nm):
νr=3×108650×10−9≈4.62×1014 Hz\nu_r = \frac{3\times 10^8}{650\times 10^{-9}} \approx 4.62\times 10^{14}\,\text{Hz}νr​=650×10−93×108​≈4.62×1014Hz

So,

νr<ν0\nu_r < \nu_0νr​<ν0​

Hence red light cannot eject electrons.

  • Blue light (λ≈450 nm\lambda \approx 450\,\text{nm}λ≈450nm):
νb=3×108450×10−9≈6.67×1014 Hz\nu_b = \frac{3\times 10^8}{450\times 10^{-9}} \approx 6.67\times 10^{14}\,\text{Hz}νb​=450×10−93×108​≈6.67×1014Hz

So,

νb>ν0\nu_b > \nu_0νb​>ν0​

Hence blue light can eject electrons.

  • White light contains many frequencies, including blue/violet and also yellow. Since it contains frequencies greater than threshold, photoelectric emission occurs.

  1. Check each statement

Statement A

When Cs is illuminated with yellow light, current is observed.

Since yellow light has frequency just above threshold, photoelectrons are emitted.

So A is correct.


Statement B

If brightness of yellow light is reduced, the ammeter current is reduced.

For light above threshold, photocurrent depends on intensity (brightness). Lower intensity means fewer emitted electrons per second, hence lower current.

So B is correct.


Statement C

If red light is used instead of yellow light, current produced is higher.

Red light has frequency below threshold, so no photoelectrons are emitted. Thus current is not higher; it is essentially zero.

So C is incorrect.


Statement D

If blue light is used, current is observed.

Blue light has frequency above threshold, so photoelectric emission occurs.

So D is correct.


Statement E

If white light is used, current is observed.

White light contains frequencies above threshold, so electrons are emitted.

So E is correct.


  1. Correct set of statements

The correct statements are:

A, B, D, EA,\ B,\ D,\ EA, B, D, E

This corresponds to Option C.


  1. Comparison with stored answer

Stored correct answer: C

My derived answer: C

So they agree.

PreviousNext

More from Structure of Atom

  • The extra stability of half-filled subshell is due to : (A) Symmetrical distribution of electrons (B) Smaller coulombic repulsion energy (C) The presence of electrons with the same spin in non-degenerate orbitals (D) Larger exchange energy…2025 · MCQ
  • The energy of an electron in the first Bohr orbit of the H-atom is -13.6 eV. The magnitude of energy value of an electron in the first excited state of Be3+ is ​ eV (nearest integer value).2025 · Numerical
  • Correct statements for an element with atomic number 9 are: A. There can be 5 electrons for which ms​=+21​ and 4 electrons for which ms​=−21​. B. There is only one electron in pz​ orbital. C. The last electron…2025 · MCQ
  • Radius of the first excited state of Helium ion is given as : a0​→ radius of first stationary state of hydrogen atom.2025 · MCQ
  • Given below are two statements : Statement (I) : A spectral line will be observed for a 2px​→2py​ transition. Statement (II) : 2px​ and 2py​ are degenerate orbitals. In the light of the above…2025 · MCQ
  • Heat treatment of muscular pain involves radiation of wavelength of about 900 nm . Which spectral line of H atom is suitable for this? Given : Rydberg constant RH​=105 cm−1, h=6.6×10−34 J s,c=3×108 m/s)…2025 · MCQ
  • Given below are two statements : Statement (I) : For a given shell, the total number of allowed orbitals is given by n2. Statement (II) : For any subshell, the spatial orientation of the orbitals is given by −l to +l values…2025 · MCQ
  • Given below are two statements about X-ray spectra of elements : Statement (I) : A plot of v​(v= frequency of X-rays emitted) vs atomic mass is a straight line. Statement (II) : A plot of v(u= frequency of X-rays emitted) vs…2025 · MCQ