JEE MainChemistryStructure of AtomMCQ+4 / −1
The extra stability of half-filled subshell is due to : (A) Symmetrical distribution of electrons (B) Smaller coulombic repulsion energy (C) The presence of electrons with the same spin in non-degenerate orbitals (D) Larger exchange energy (E) Relatively smaller shielding of electrons by one another Indentify the correct statements :
- A(B), (D) and (E) only
- Band (E) only
- C(B), (C) and (D) only
- Dand (D) only
View written solutionFree
Correct answer: B
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Concept: why half-filled subshells are extra stable
Half-filled and completely filled subshells show extra stability mainly due to:
- symmetrical distribution of electrons,
- maximum exchange energy,
- and relatively lower electron-electron repulsion in such arrangements.
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Examine each statement
(A) Symmetrical distribution of electrons
- In a half-filled subshell, electrons occupy all orbitals singly.
- This gives a symmetrical arrangement, which is more stable.
- Hence, (A) is correct.
(B) Smaller coulombic repulsion energy
- In a half-filled subshell, electrons remain unpaired in different orbitals before pairing occurs.
- This reduces electron-electron repulsion compared to paired arrangements.
- Hence, (B) is correct.
(C) The presence of electrons with the same spin in non-degenerate orbitals
- Exchange energy arises when electrons with parallel spin are present in degenerate orbitals, not non-degenerate orbitals.
- Since the statement says non-degenerate orbitals, it is incorrect.
- Hence, (C) is incorrect.
(D) Larger exchange energy
- A half-filled subshell has the maximum number of possible exchanges among electrons with parallel spins.
- Greater exchange energy leads to greater stability.
- Hence, (D) is correct.
(E) Relatively smaller shielding of electrons by one another
- In standard explanation for extra stability of half-filled subshells, this is also considered a contributing factor.
- Hence, (E) is correct.
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Collect correct statements
Correct statements are:
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Match with the given options
This corresponds to Option B.
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Comparison with stored answer
Stored correct answer: B
Our derived answer: B
So, the answers agree.
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