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Salt Analysis question

2022 · 24 Jun · Shift 2 · Q14
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Salt Analysis question

2022 · 24 Jun · Shift 2 · Q14

JEE MainChemistrySalt AnalysisMCQ+4 / −1
In the flame test of a mixture of salts, a green flame with blue centre was observed. Which one of the following cations may be present?
  1. A
    Cu2+Cu^{2+}Cu2+
  2. B
    Sr2+Sr^{2+}Sr2+
  3. C
    Ba2+Ba^{2+}Ba2+
  4. D
    Ca2+Ca^{2+}Ca2+
View written solutionFree

Correct answer: A

  1. Recall characteristic flame test colours

    In flame tests, different metal cations impart characteristic colours:

    • Cu2+Cu^{2+}Cu2+ : green flame, often with a blue centre
    • Sr2+Sr^{2+}Sr2+ : crimson red
    • Ba2+Ba^{2+}Ba2+ : apple green
    • Ca2+Ca^{2+}Ca2+ : brick red
  2. Match the observed flame colour

    The observation given is:

    green flame with blue centre\text{green flame with blue centre}green flame with blue centre

    This is the characteristic flame of copper salts.

  3. Check each option

    • A: Cu2+Cu^{2+}Cu2+ — matches the observed flame colour. ✅
    • B: Sr2+Sr^{2+}Sr2+ — gives crimson red flame, not correct. ❌
    • C: Ba2+Ba^{2+}Ba2+ — gives apple green, but not typically described as green with blue centre. ❌
    • D: Ca2+Ca^{2+}Ca2+ — gives brick red flame, not correct. ❌
  4. Final answer

    Therefore, the cation present may be:

    Cu2+\boxed{Cu^{2+}}Cu2+​

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