Match the following : .tg border-collapse:collapse;border-spacing:0; .tg tdborder-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px; overflow:hidden;padding:10px 5px;word-break:normal; .tg thborder-color:black;border-style:solid;border-width:1px;font-family:Arial, sans-serif;font-size:14px; font-weight:normal;overflow:hidden;padding:10px 5px;word-break:normal; .tg .tg-baqhtext-align:center;vertical-align:top Test/Method Reagent (i) Lucas Test (a) C 6 H 5 SO 2 Cl/ aq. KOH (ii) Dumas method (b) HNO 3 / AgNO 3 (iii) Kjeldahl’s method (c) CuO/CO 2 (iv) Hinsberg test (d) Conc. HCl and ZnCl 2 (e) H 2 SO 4

(i)-(d), (ii)-(c), (iii)-(e), (iv)-(a)

(i)-(b), (ii)-(d), (iii)-(e), (iv)-(a)

(i)-(b), (ii)-(a), (iii)-(c), (iv)-(d)

(i)-(d), (ii)-(c), (iii)-(b), (iv)-(e)

Salt Analysis PYQ — JEE Main 2020 · 6 Sep · Shift 2 · Q13 with Solution

Match the following :

View written solutionFree

Correct answer: B

We match each test/method with its correct reagent.
Lucas Test
- Lucas test is used to distinguish alcohols.
- Reagent used: conc. HCl and anhydrous ZnCl $_2$ .
- So, $\text{(i) Lucas Test} \to \text{(d) Conc. HCl and ZnCl}_2$
Dumas method
- Dumas method is used for estimation of nitrogen.
- The organic compound is heated with CuO, and nitrogen is measured after conversion of C and H into oxides.
- Among the given options, this corresponds to: $\text{(ii) Dumas method} \to \text{(c) CuO/CO}_2$
Kjeldahl’s method
- Kjeldahl’s method involves digestion with concentrated H $_2$ SO $_4$ .
- Hence, $\text{(iii) Kjeldahl's method} \to \text{(e) H}_2\text{SO}_4$
Hinsberg test
- Hinsberg test for amines uses benzenesulphonyl chloride in aqueous KOH.
- Therefore, $\text{(iv) Hinsberg test} \to \text{(a) C}_6\text{H}_5\text{SO}_2\text{Cl / aq. KOH}$
Final matching:
$(i)-(d), \quad (ii)-(c), \quad (iii)-(e), \quad (iv)-(a)$
Compare with options:
- This corresponds to Option B.

Answer: $\boxed{\text{B}}$