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Salt Analysis question

2021 · 20 Jul · Shift 2 · Q14
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  5. /2021 · 20 Jul · Shift 2 · Q14

Salt Analysis question

2021 · 20 Jul · Shift 2 · Q14

JEE MainChemistrySalt AnalysisMCQ+4 / −1
Cu2+Cu^{2+}Cu2+ salt reacts with potassium iodide to give
  1. A
    Cu2I2Cu_2I_2Cu2​I2​
  2. B
    Cu2I3Cu_2I_3Cu2​I3​
  3. C
    Cul
  4. D
    Cu(I3)2Cu(I_3)_2Cu(I3​)2​
View written solutionFree

Correct answer: C

  1. Identify the reaction involved

When a salt containing Cu2+Cu^{2+}Cu2+ reacts with potassium iodide, iodide ion I−I^-I− acts as a reducing agent.

So, Cu2+Cu^{2+}Cu2+ is reduced to Cu+Cu^+Cu+ and iodide is oxidized to iodine.

  1. Write the ionic change

The redox process is:

2Cu2++4I−→2CuI+I22Cu^{2+} + 4I^- \rightarrow 2CuI + I_22Cu2++4I−→2CuI+I2​

  1. Nature of the copper product

The Cu+Cu^+Cu+ formed combines with I−I^-I− to give cuprous iodide:

Cu++I−→CuICu^+ + I^- \rightarrow CuICu++I−→CuI

Cuprous iodide is insoluble and precipitates as a white solid.

  1. Check the options
  • A: Cu2I2Cu_2I_2Cu2​I2​
    This is just the dimeric representation of CuICuICuI, but the standard formula of cuprous iodide is CuICuICuI.
  • B: Cu2I3Cu_2I_3Cu2​I3​
    Incorrect formula.
  • C: CuICuICuI
    Correct. This is cuprous iodide formed in the reaction.
  • D: Cu(I3)2Cu(I_3)_2Cu(I3​)2​
    Incorrect in this context.
  1. Final answer

The product formed is:

CuI\boxed{CuI}CuI​

So, the correct option is C.

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