JEE MainChemistrySalt AnalysisMCQ+4 / −1
A solution containing a group-IV cation gives a precipitate on passing . A solution of this precipitate in dil. produces a white precipitate with solution and bluish-white precipitate with basic potassium ferrocyanide. The cation is :
- A
- B
- C
- D
View written solutionFree
Correct answer: D
-
Identify the relevant group-IV cations
In classical salt analysis, the common group-IV cations are: These are precipitated as sulphides by passing in ammoniacal/basic medium. -
Given: the cation gives a precipitate with
So the cation forms its sulphide: This is consistent with all four options. -
The precipitate dissolves in dilute
Now test the resulting solution. -
Test with gives a white precipitate
Let us compare the hydroxides formed:- : bluish / dirty precipitate
- : green precipitate
- : white precipitate, but quickly turns brown on oxidation
- : white gelatinous precipitate
So at this stage, the likely ions are:
-
Test with basic potassium ferrocyanide gives a bluish-white precipitate
Characteristic observations:- gives a bluish-white precipitate with basic potassium ferrocyanide.
- does not give this characteristic bluish-white precipitate.
- and give different colored precipitates.
Therefore, the cation must be:
-
Evaluate options
- A: — incorrect
- B: — incorrect
- C: — incorrect
- D: — correct
Final Answer
So, the correct option is D.
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