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Salt Analysis question

2017 · 8 Apr · Shift 1 · Q7
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Salt Analysis question

2017 · 8 Apr · Shift 1 · Q7

JEE MainChemistrySalt AnalysisMCQ+4 / −1
A solution containing a group-IV cation gives a precipitate on passing H2SH_2SH2​S. A solution of this precipitate in dil.HClHClHCl produces a white precipitate with NaOHNaOHNaOH solution and bluish-white precipitate with basic potassium ferrocyanide. The cation is :
  1. A
    Co2+Co^{2+}Co2+
  2. B
    Ni2+Ni^{2+}Ni2+
  3. C
    Mn2+Mn^{2+}Mn2+
  4. D
    Zn2+Zn^{2+}Zn2+
View written solutionFree

Correct answer: D

  1. Identify the relevant group-IV cations
    In classical salt analysis, the common group-IV cations are: Zn2+, Mn2+, Ni2+, Co2+Zn^{2+},\ Mn^{2+},\ Ni^{2+},\ Co^{2+}Zn2+, Mn2+, Ni2+, Co2+ These are precipitated as sulphides by passing H2SH_2SH2​S in ammoniacal/basic medium.

  2. Given: the cation gives a precipitate with H2SH_2SH2​S
    So the cation forms its sulphide: MSMSMS This is consistent with all four options.

  3. The precipitate dissolves in dilute HClHClHCl
    Now test the resulting solution.

  4. Test with NaOHNaOHNaOH gives a white precipitate
    Let us compare the hydroxides formed:

    • Co(OH)2Co(OH)_2Co(OH)2​ : bluish / dirty precipitate
    • Ni(OH)2Ni(OH)_2Ni(OH)2​ : green precipitate
    • Mn(OH)2Mn(OH)_2Mn(OH)2​ : white precipitate, but quickly turns brown on oxidation
    • Zn(OH)2Zn(OH)_2Zn(OH)2​ : white gelatinous precipitate

    So at this stage, the likely ions are: Mn2+ or Zn2+Mn^{2+} \text{ or } Zn^{2+}Mn2+ or Zn2+

  5. Test with basic potassium ferrocyanide gives a bluish-white precipitate
    Characteristic observations:

    • Zn2+Zn^{2+}Zn2+ gives a bluish-white precipitate with basic potassium ferrocyanide.
    • Mn2+Mn^{2+}Mn2+ does not give this characteristic bluish-white precipitate.
    • Ni2+Ni^{2+}Ni2+ and Co2+Co^{2+}Co2+ give different colored precipitates.

    Therefore, the cation must be: Zn2+Zn^{2+}Zn2+

  6. Evaluate options

    • A: Co2+Co^{2+}Co2+ — incorrect
    • B: Ni2+Ni^{2+}Ni2+ — incorrect
    • C: Mn2+Mn^{2+}Mn2+ — incorrect
    • D: Zn2+Zn^{2+}Zn2+ — correct

Final Answer

Zn2+\boxed{Zn^{2+}}Zn2+​ So, the correct option is D.

Previous

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