Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Redox Reactions question

2022 · 29 Jul · Shift 2 · Q15
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Redox Reactions
  5. /2022 · 29 Jul · Shift 2 · Q15

Redox Reactions question

2022 · 29 Jul · Shift 2 · Q15

JEE MainChemistryRedox ReactionsMCQ+4 / −1
A compound 'X' is a weak acid and it exhibits colour change at pH close to the equivalence point during neutralization of NaOH with CH3COOH\mathrm{CH}_{3} \mathrm{COOH}CH3​COOH. Compound 'X' exists in ionized form in basic medium. The compound 'X' is
  1. A
    methyl orange
  2. B
    methyl red
  3. C
    phenolphthalein
  4. D
    erichrome Black T
View written solutionFree

Correct answer: C

  1. Identify the titration type

    The neutralization is: CH3COOH+NaOH→CH3COONa+H2O\mathrm{CH_3COOH + NaOH \rightarrow CH_3COONa + H_2O}CH3​COOH+NaOH→CH3​COONa+H2​O

    Here:

    • CH3COOH\mathrm{CH_3COOH}CH3​COOH is a weak acid
    • NaOH\mathrm{NaOH}NaOH is a strong base

    So this is a weak acid–strong base titration.

  2. Locate the equivalence point pH

    In a weak acid–strong base titration, the equivalence point lies in the basic range: pH at equivalence point>7\text{pH at equivalence point} > 7pH at equivalence point>7

    Therefore, the suitable indicator must change colour in the basic pH range near the equivalence point.

  3. Use the condition about the indicator

    The question says compound XXX:

    • is a weak acid
    • shows colour change near the equivalence point
    • exists in ionized form in basic medium

    This matches the general behavior of acid-base indicators: HIn⇌H++In−\mathrm{HIn \rightleftharpoons H^+ + In^-}HIn⇌H++In−

    In basic medium, equilibrium shifts right, so the indicator exists mainly as the ionized form In−\mathrm{In^-}In−.

  4. Check the options

    A. Methyl orange

    • Transition range: about 3.13.13.1 to 4.44.44.4
    • Suitable for strong acid–weak base titrations, not weak acid–strong base.
    • Not correct.

    B. Methyl red

    • Transition range: about 4.44.44.4 to 6.26.26.2
    • Also too low for the basic equivalence point of acetic acid vs NaOH.
    • Not correct.

    C. Phenolphthalein

    • Transition range: about 8.28.28.2 to 10.010.010.0
    • Ideal for weak acid–strong base titration.
    • It is a weak acid indicator and in basic medium it exists in ionized form with a pink colour.
    • Correct.

    D. Eriochrome Black T

    • Used mainly in complexometric titrations, not as the proper indicator here.
    • Not correct.
  5. Final conclusion

    The compound XXX is: Phenolphthalein\boxed{\text{Phenolphthalein}}Phenolphthalein​

  6. Comparison with stored answer

    Stored correct answer: C

    Our derived answer: C

    Hence, the derived answer agrees with the stored answer.

PreviousNext

More from Redox Reactions

  • Statement I : Sodium hydride can be used as an oxidising agent. Statement II : The lone pair of electrons on nitrogen in pyridine makes it basic. Choose the CORRECT answer from the options given below :2021 · MCQ
  • The oxidation states of nitrogen in NO, NO2​, N2​O and NO 3−​ are in the order of :2021 · MCQ
  • 0.4 g mixture of NaOH, Na2​CO3​ and some inert impurities was first titrated with 10N​ HCl using phenolphthalein as an indicator, 17.5 mL of HCl was required at the end point. After this methyl orange was added and…2021 · Numerical
  • Identify the process in which change in the oxidation state is five :2021 · MCQ
  • Dichromate ion is treated with base, the oxidation number of Cr in the product formed is ​.2021 · Numerical
  • The oxidation states of 'P' in H4​P2​O7​, H4​P2​O5​ and H4​P2​O6​, respectively, are :2021 · MCQ
  • 10.0 mL of 0.05 M KMnO4​ solution was consumed in a titration with 10.0 mL of given oxalic acid dihydrate solution. The strength of given oxalic acid solution is ​× 10 − 2 g/L. (Round off to the nearest…2021 · Numerical
  • While titrating dilute HCl solution with aqueous NaOH, which of the following will not be required?2020 · MCQ