JEE MainChemistryRedox ReactionsNumerical+4 / −1
0.4 g mixture of , and some inert impurities was first titrated with using phenolphthalein as an indicator, 17.5 mL of was required at the end point. After this methyl orange was added and titrated. 1.5 mL of same was required for the next end point. The weight percentage of in the mixture is . (Rounded off to the nearest integer)
Numerical answer
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Correct answer: 4
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Let the amounts be:
- Moles of
- Moles of
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Reaction with up to phenolphthalein end point:
Phenolphthalein end point corresponds to:
- complete neutralization of
- conversion of to
So, acid consumed:
Given of is used.
Since is monoprotic,
Therefore,
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Reaction from phenolphthalein to methyl orange end point:
Now only formed from is neutralized:
Hence acid consumed in second stage equals moles of .
Given additional of :
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**Mass of : **
Molar mass of g/mol.
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Weight percentage in 0.4 g mixture:
Rounded to nearest integer:
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Final Answer:
The weight percentage of is:
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