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Redox Reactions question

2021 · 27 Jul · Shift 2 · Q16
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Redox Reactions question

2021 · 27 Jul · Shift 2 · Q16

JEE MainChemistryRedox ReactionsNumerical+4 / −1
10.0 mL of 0.05 M KMnO4KMnO_4KMnO4​ solution was consumed in a titration with 10.0 mL of given oxalic acid dihydrate solution. The strength of given oxalic acid solution is ‾×\underline{\hspace{2cm}}\times​× 10 −-− 2 g/L. (Round off to the nearest integer)
Numerical answer
View written solutionFree

Correct answer: 1575

  1. Write the balanced redox reaction

In acidic medium, potassium permanganate oxidizes oxalic acid:

2KMnO4+5H2C2O4+3H2SO4→K2SO4+2MnSO4+10CO2+8H2O2KMnO_4 + 5H_2C_2O_4 + 3H_2SO_4 \rightarrow K_2SO_4 + 2MnSO_4 + 10CO_2 + 8H_2O2KMnO4​+5H2​C2​O4​+3H2​SO4​→K2​SO4​+2MnSO4​+10CO2​+8H2​O

So, the mole ratio is:

2 mol KMnO4:5 mol oxalic acid2\text{ mol } KMnO_4 : 5\text{ mol oxalic acid}2 mol KMnO4​:5 mol oxalic acid


  1. Moles of KMnO4KMnO_4KMnO4​ used

Given:

  • Volume of KMnO4=10.0 mL=0.0100 LKMnO_4 = 10.0\,\text{mL} = 0.0100\,\text{L}KMnO4​=10.0mL=0.0100L
  • Molarity of KMnO4=0.05 MKMnO_4 = 0.05\,MKMnO4​=0.05M

Therefore,

moles of KMnO4=M×V=0.05×0.0100=5.0×10−4\text{moles of } KMnO_4 = M \times V = 0.05 \times 0.0100 = 5.0 \times 10^{-4}moles of KMnO4​=M×V=0.05×0.0100=5.0×10−4


  1. Moles of oxalic acid dihydrate reacted

Using the stoichiometric ratio:

moles of oxalic acidmoles of KMnO4=52\frac{\text{moles of oxalic acid}}{\text{moles of } KMnO_4} = \frac{5}{2}moles of KMnO4​moles of oxalic acid​=25​

Hence,

moles of oxalic acid dihydrate=52×5.0×10−4=1.25×10−3\text{moles of oxalic acid dihydrate} = \frac{5}{2} \times 5.0 \times 10^{-4} = 1.25 \times 10^{-3}moles of oxalic acid dihydrate=25​×5.0×10−4=1.25×10−3

These moles are present in 10.0 mL10.0\,\text{mL}10.0mL of the given solution.


  1. Find molarity of oxalic acid dihydrate solution

Volume of oxalic acid solution =10.0 mL=0.0100 L= 10.0\,\text{mL} = 0.0100\,\text{L}=10.0mL=0.0100L

M=1.25×10−30.0100=0.125 MM = \frac{1.25 \times 10^{-3}}{0.0100} = 0.125\,MM=0.01001.25×10−3​=0.125M


  1. Calculate strength in g/L

Given oxalic acid is oxalic acid dihydrate:

H2C2O4⋅2H2OH_2C_2O_4\cdot 2H_2OH2​C2​O4​⋅2H2​O

Molar mass:

=2(1)+2(12)+4(16)+2(18)=2+24+64+36=126 g/mol= 2(1) + 2(12) + 4(16) + 2(18) = 2 + 24 + 64 + 36 = 126\,\text{g/mol}=2(1)+2(12)+4(16)+2(18)=2+24+64+36=126g/mol

Strength:

Strength=M×molar mass=0.125×126=15.75 g/L\text{Strength} = M \times \text{molar mass} = 0.125 \times 126 = 15.75\,\text{g/L}Strength=M×molar mass=0.125×126=15.75g/L


  1. Match with the required format

They ask for:

‾×10−2 g/L\underline{\hspace{2cm}} \times 10^{-2}\,\text{g/L}​×10−2g/L

Now,

15.75 g/L=1575×10−2 g/L15.75\,\text{g/L} = 1575 \times 10^{-2}\,\text{g/L}15.75g/L=1575×10−2g/L

Rounded to the nearest integer, the required number is:

1575\boxed{1575}1575​


  1. Comparison with stored answer

Stored correct answer = 157515751575

My derived answer also = 157515751575

So the answer agrees.

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