JEE MainChemistryRedox ReactionsMCQ+4 / −1
Given below are two statements: one is labelled as Assertion and the other is labelled as Reason . Assertion A: Phenolphthalein is a dependent indicator, remains colourless in acidic solution and gives pink colour in basic medium. Reason R: Phenolphthalein is a weak acid. It doesn't dissociate in basic medium. In the light of the above statements, choose the most appropriate answer from the options given below.
- ABoth and are true and is the correct explanation of .
- BBoth and are true but is NOT the correct explanation of .
- CA is true but R is false.
- DA is false but R is true.
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Correct answer: C
- Check Assertion A
Phenolphthalein is an acid–base indicator.
- In acidic medium, it remains colourless.
- In basic medium, it turns pink.
This is a standard property of phenolphthalein.
So, Assertion A is true.
- Check Reason R
Reason says:
Phenolphthalein is a weak acid. It doesn't dissociate in basic medium.
Let us analyze this carefully.
Phenolphthalein behaves as a weak acid indicator and can be represented as:
- The undissociated form is colourless.
- The dissociated/anionic form in basic medium is pink.
In basic medium, due to removal of by , the equilibrium shifts to the right, so phenolphthalein does dissociate more in basic medium, producing the pink ionized form.
Hence the statement "It doesn't dissociate in basic medium" is false.
Therefore, Reason R is false.
- Select the correct option
- Assertion A: True
- Reason R: False
So the correct option is:
- Comparison with stored correct answer
Stored correct answer = C
Our derived answer = C
So, the derived answer agrees with the stored correct answer.
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