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Redox Reactions question

2019 · 12 Jan · Shift 1 · Q12
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Redox Reactions question

2019 · 12 Jan · Shift 1 · Q12

JEE MainChemistryRedox ReactionsMCQ+4 / −1
The hardness of a water sample (in terms of equivalents of CaCO3CaCO_3CaCO3​) containing 10–3 M CaSO4CaSO_4CaSO4​ is (Molar mass of CaSO4CaSO_4CaSO4​ = 136 g mol–1)
  1. A
    90 ppm
  2. B
    100 ppm
  3. C
    50 ppm
  4. D
    10 ppm
View written solutionFree

Correct answer: B

  1. Meaning of hardness in terms of CaCO3CaCO_3CaCO3​

    Hardness is often expressed as the equivalent concentration of CaCO3CaCO_3CaCO3​.

    For this, we use: Hardness as CaCO3=Normality of hardness-producing salt×equivalent weight of CaCO3\text{Hardness as } CaCO_3 = \text{Normality of hardness-producing salt} \times \text{equivalent weight of } CaCO_3Hardness as CaCO3​=Normality of hardness-producing salt×equivalent weight of CaCO3​

  2. Given concentration of CaSO4CaSO_4CaSO4​

    [CaSO4]=10−3 M[CaSO_4] = 10^{-3}\,M[CaSO4​]=10−3M

    Since CaSO4CaSO_4CaSO4​ gives one Ca2+Ca^{2+}Ca2+ ion per formula unit, its valency factor is 222.

    Therefore, its normality is: N=M×2=10−3×2=2×10−3 NN = M \times 2 = 10^{-3} \times 2 = 2 \times 10^{-3}\,NN=M×2=10−3×2=2×10−3N

  3. Equivalent weight of CaCO3CaCO_3CaCO3​

    Molar mass of CaCO3=100CaCO_3 = 100CaCO3​=100 g/mol

    Since CaCO3CaCO_3CaCO3​ also has valency factor 222, Eq. wt. of CaCO3=1002=50 g/eq\text{Eq. wt. of } CaCO_3 = \frac{100}{2} = 50\,g/eqEq. wt. of CaCO3​=2100​=50g/eq

  4. Convert to grams per litre as CaCO3CaCO_3CaCO3​

    Hardness=N×eq. wt.=2×10−3×50=0.1 g/L\text{Hardness} = N \times \text{eq. wt.} = 2 \times 10^{-3} \times 50 = 0.1\,g/LHardness=N×eq. wt.=2×10−3×50=0.1g/L

    0.1 g/L=100 mg/L0.1\,g/L = 100\,mg/L0.1g/L=100mg/L

  5. Convert mg/L to ppm

    For dilute aqueous solutions, 1 mg/L≈1 ppm1\,mg/L \approx 1\,ppm1mg/L≈1ppm

    Hence, 100 mg/L=100 ppm100\,mg/L = 100\,ppm100mg/L=100ppm

  6. Option check

    • A: 909090 ppm →\rightarrow→ incorrect
    • B: 100100100 ppm →\rightarrow→ correct
    • C: 505050 ppm →\rightarrow→ incorrect
    • D: 101010 ppm →\rightarrow→ incorrect

Therefore, the hardness of water sample is: 100 ppm\boxed{100\,ppm}100ppm​

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