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Redox Reactions question

2002 · Shift 0 · Q36
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Redox Reactions question

2002 · Shift 0 · Q36

JEE MainChemistryRedox ReactionsMCQ+4 / −1
Which of the following is a redox reaction ?
  1. A
    NaClNaClNaCl + KNO3KNO_3KNO3​ →\to→ NaNO3NaNO_3NaNO3​ + KClKClKCl
  2. B
    CaC2O4CaC_2O_4CaC2​O4​ + 2HClHClHCl →\to→ CaCl2CaCl_2CaCl2​ + H2C2O4H_2C_2O_4H2​C2​O4​
  3. C
    Mg(OH)2Mg(OH)_2Mg(OH)2​ + 2NH4ClNH_4ClNH4​Cl →\to→ MgCl2MgCl_2MgCl2​ + 2NH4OHNH_4OHNH4​OH
  4. D
    ZnZnZn + 2AgCNAgCNAgCN →\to→ 2Ag+Ag^+Ag+ Zn(CN)2Zn(CN)_2Zn(CN)2​
View written solutionFree

Correct answer: D

  1. A reaction is redox if oxidation numbers change in the process.

We check each option.


  1. Option A:

NaCl+KNO3→NaNO3+KClNaCl + KNO_3 \to NaNO_3 + KClNaCl+KNO3​→NaNO3​+KCl

This is just exchange of ions.

  • NaNaNa remains +1+1+1
  • KKK remains +1+1+1
  • ClClCl remains −1-1−1
  • In NO3−NO_3^-NO3−​, NNN is +5+5+5, OOO is −2-2−2

No oxidation number changes.

So, A is not a redox reaction.


  1. Option B:

CaC2O4+2HCl→CaCl2+H2C2O4CaC_2O_4 + 2HCl \to CaCl_2 + H_2C_2O_4CaC2​O4​+2HCl→CaCl2​+H2​C2​O4​

This is an acid-salt reaction.

Check oxidation numbers:

  • CaCaCa is +2+2+2 on both sides.
  • In C2O42−C_2O_4^{2-}C2​O42−​, let oxidation state of each CCC be xxx: 2x+4(−2)=−22x + 4(-2) = -22x+4(−2)=−2 2x−8=−22x - 8 = -22x−8=−2 2x=62x = 62x=6 x=+3x = +3x=+3

In H2C2O4H_2C_2O_4H2​C2​O4​, carbon is still +3+3+3.

  • ClClCl remains −1-1−1
  • HHH remains +1+1+1

No oxidation number changes.

So, B is not a redox reaction.


  1. Option C:

Mg(OH)2+2NH4Cl→MgCl2+2NH4OHMg(OH)_2 + 2NH_4Cl \to MgCl_2 + 2NH_4OHMg(OH)2​+2NH4​Cl→MgCl2​+2NH4​OH

This is also a double displacement / acid-base type reaction.

  • MgMgMg remains +2+2+2
  • In NH4+NH_4^+NH4+​, NNN is −3-3−3 and remains −3-3−3
  • ClClCl remains −1-1−1
  • OOO remains −2-2−2, HHH remains +1+1+1

No oxidation number changes.

So, C is not a redox reaction.


  1. Option D:

The intended reaction is:

Zn+2AgCN→2Ag+Zn(CN)2Zn + 2AgCN \to 2Ag + Zn(CN)_2Zn+2AgCN→2Ag+Zn(CN)2​

(There appears to be a typo in the printed product; silver should be formed as AgAgAg, not Ag+Ag^+Ag+, for the reaction to balance as a redox displacement.)

Now check oxidation numbers:

  • ZnZnZn in elemental form: 000
  • In Zn(CN)2Zn(CN)_2Zn(CN)2​, zinc is +2+2+2

So zinc is oxidized:

Zn0→Zn2++2e−Zn^0 \to Zn^{2+} + 2e^-Zn0→Zn2++2e−

In AgCNAgCNAgCN, the cyanide ion is CN−CN^-CN−, so AgAgAg is +1+1+1. In product, AgAgAg is elemental silver, so oxidation state is 000.

Thus silver is reduced:

2Ag++2e−→2Ag2Ag^+ + 2e^- \to 2Ag2Ag++2e−→2Ag

Since oxidation and reduction both occur, D is a redox reaction.


  1. Conclusion

The redox reaction is:

D\boxed{D}D​

Previous

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