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Redox Reactions question

2017 · Shift 0 · Q15
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Redox Reactions question

2017 · Shift 0 · Q15

JEE MainChemistryRedox ReactionsMCQ+4 / −1
Which of the following reactions is an example of a redox reaction?
  1. A
    XeF6Xe{F_6}XeF6​+ H2OH_2OH2​O →XeOF4\to XeO{F_4}→XeOF4​ + 2HFHFHF
  2. B
    XeF6Xe{F_6}XeF6​+ 2H2OH_2OH2​O →XeO2F2\to XeO_2{F_2}→XeO2​F2​ + 4HFHFHF
  3. C
    XeF4Xe{F_4}XeF4​+ O2F2O_2F_2O2​F2​ →XeF6\to Xe{F_6}→XeF6​ + O2O_2O2​
  4. D
    XeF2Xe{F_2}XeF2​+ PF5PF_5PF5​ →\to→ [XeF]+PF6−{\left[ {XeF} \right]^ + }PF_6^ -[XeF]+PF6−​
View written solutionFree

Correct answer: C

  1. Criterion for a redox reaction

A reaction is redox if at least one element undergoes oxidation number change.

So, we check oxidation states in each option.


  1. Option A

XeF6+H2O→XeOF4+2HFXeF_6 + H_2O \to XeOF_4 + 2HFXeF6​+H2​O→XeOF4​+2HF

Let oxidation state of Xe in XeF6XeF_6XeF6​ be xxx:

x+6(−1)=0⇒x=+6x + 6(-1)=0 \Rightarrow x=+6x+6(−1)=0⇒x=+6

Now in XeOF4XeOF_4XeOF4​:

x+(−2)+4(−1)=0x + (-2) + 4(-1)=0x+(−2)+4(−1)=0 x−2−4=0x-2-4=0x−2−4=0 x=+6x=+6x=+6

Xe remains +6+6+6.

Hydrogen, oxygen, fluorine also keep their usual oxidation states.

So this is not a redox reaction.


  1. Option B

XeF6+2H2O→XeO2F2+4HFXeF_6 + 2H_2O \to XeO_2F_2 + 4HFXeF6​+2H2​O→XeO2​F2​+4HF

In XeF6XeF_6XeF6​, Xe is:

x+6(−1)=0⇒x=+6x+6(-1)=0 \Rightarrow x=+6x+6(−1)=0⇒x=+6

In XeO2F2XeO_2F_2XeO2​F2​:

x+2(−2)+2(−1)=0x+2(-2)+2(-1)=0x+2(−2)+2(−1)=0 x−4−2=0x-4-2=0x−4−2=0 x=+6x=+6x=+6

Again, Xe remains +6+6+6.

Hence this is not redox.


  1. Option C

XeF4+O2F2→XeF6+O2XeF_4 + O_2F_2 \to XeF_6 + O_2XeF4​+O2​F2​→XeF6​+O2​

First, Xe in XeF4XeF_4XeF4​:

x+4(−1)=0⇒x=+4x+4(-1)=0 \Rightarrow x=+4x+4(−1)=0⇒x=+4

Xe in XeF6XeF_6XeF6​:

x+6(−1)=0⇒x=+6x+6(-1)=0 \Rightarrow x=+6x+6(−1)=0⇒x=+6

So Xe is oxidized from +4+4+4 to +6+6+6.

Now check oxygen in O2F2O_2F_2O2​F2​.

Let oxidation state of O be xxx:

2x+2(−1)=02x+2(-1)=02x+2(−1)=0 2x−2=02x-2=02x−2=0 x=+1x=+1x=+1

In O2O_2O2​, oxygen is 000.

So O changes from +1+1+1 to 000, hence oxygen is reduced.

Therefore, oxidation and reduction both occur.

So Option C is a redox reaction.


  1. Option D

XeF2+PF5→[XeF]+PF6−XeF_2 + PF_5 \to [XeF]^+ PF_6^-XeF2​+PF5​→[XeF]+PF6−​

In XeF2XeF_2XeF2​, Xe is:

x+2(−1)=0⇒x=+2x+2(-1)=0 \Rightarrow x=+2x+2(−1)=0⇒x=+2

In [XeF]+[XeF]^+[XeF]+:

x+(−1)=+1x+(-1)=+1x+(−1)=+1 x=+2x=+2x=+2

Xe remains +2+2+2.

For phosphorus:

In PF5PF_5PF5​:

x+5(−1)=0⇒x=+5x+5(-1)=0 \Rightarrow x=+5x+5(−1)=0⇒x=+5

In PF6−PF_6^-PF6−​:

x+6(−1)=−1x+6(-1)=-1x+6(−1)=−1 x−6=−1x-6=-1x−6=−1 x=+5x=+5x=+5

P also remains +5+5+5.

Hence this is not redox.


  1. Conclusion

Only Option C involves change in oxidation numbers, so it is the redox reaction.


  1. Comparison with stored correct answer

Stored correct answer: C

My derived answer: C

They agree.

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